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SOLUTION TO EXERCISE 14
SOLUTION TO EXERCISE 14 According to the Ideal Gas Law, P = nkT. Since T = 0 C = 273 K is the temperature of S.T.P. conditions, the number density of the gas in the vacuum chamber is directly related to the number density of gas at S.T.P. by its pressure. Since, at S.T.P., one mole of particles occupies 22.4 liters, 0.000000001 * 6 * 10^23 n = ----------------------- = 2.69 * 10^10 per cm^3 in the vacuum chamber. 22.4 l * 1000 cm^3/l (a) Again, since P = nkT, and the comet tail has T = 273 K, the same as the vacuum chamber, we can compare pressures by comparing number densities. P in vacuum chamber 2.69 * 10^10 per cm^3 --------------------- = ----------------------- = 2.69 * 10^6 P in comet tail 10,000 per cm^3 So the pressure in the chamber is about 2.69 million times greater than in the comet tail! Clearly, vacuum experiments in Earth laboratories still have a long way to go before they can mimic the vacuum of space. (b) If the comet tail's temperature is actually 3 K rather than 273 K, then the Ideal Gas Law gives us guidance again: since P = nkT, the pressure in this comet tail would be lower than that of the tail at 273 K by a factor of the temperature ratio. Thus, P in comet tail at 273 K 273 K -------------------------- = ------- = 91 P in comet tail at 3 K 3 K So the pressure in the vacuum chamber is greater that that of the 3 K comet tail by a factor of 2.69 * 10^6 * 91 = 2.45 * 10^8 (that is, a factor of 245 million). Very low! |