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OCR for page R1
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Committee on Chemical Engineering Frontiers:
Research Needs and Opportunities
Board on Chemical Sciences and Technology
.
Commission on Physical Sciences, Mathematics, and Resources
National Research Council
NATIONAL ACADEMY PRESS
Washington, D.C. 1988
OCR for page R2
NATIONAL ACADEMY PRESS
· 2101 Constitution Avenue, NW
Washington, DC 20418
NOTICE: The project that is the subject of this report was approved by the Governing Board of the National Research
Council, whose members are drawn from the councils of the National Academy of Sciences, the National Academy of
Engineering, and the Institute of Medicine. The members of the committee responsible for the report were chosen for their
special competences and with regard for appropriate balance.
This report has been reviewed by a group other than the authors according to procedures approved by a Report Review
Committee consisting of members of the National Academy of Sciences, the National Academy of Engineering, and the
Institute of Medicine.
The National Academy of Sciences is a private, nonprofit, self-perpetuating society of distinguished scholars engaged in
scientific and engineering research, dedicated to the furtherance of science and technology and to their use for the general
welfare. Upon the authority of the charter granted to it by the Congress in 1863, the Academy has a mandate that requires
it to advise the federal government on scientific and technical matters. Dr. Frank Press is president of the National Academy
of Sciences.
The National Academy of Engineering was established in 1964, under the charter of the National Academy of Sciences,
as a parallel organization of outstanding engineers. It is autonomous in its administration and in the selection of its members,
sharing with the National Academy of Sciences the responsibility for advising the federal government. The National Academy
of Engineering also sponsors engineering programs aimed at meeting national needs, encourages education and research,
and recognizes the superior achievements of engineers. Dr. Robert M. White is president of the National Academy of
~-
~ A _
Engineering.
The Institute of Medicine was established In 197U by the National Academy or Sciences to secure one services or eminent
members of appropriate professions in the examination of policy matters pertaining to the health of the public. The Institute
acts under the responsibility given to the National Academy of Sciences by its congressional charter to be an adviser to the
federal government and, upon its own initiative, to identify issues of medical care, research, and education. Dr. Samuel O.
Thier is president of the Institute of Medicine.
The National Research Council was organized by the National Academy of Sciences in 1916 to associate the broad
community of science and technology with the Academy's purposes of furthering knowledge and advising the federal
government. Functioning in accordance with general policies determined by the Academy, the 'Council has become the
principal operating agency of both the National Academy of Sciences and the National Academy of Engineering in providing
services to the government, the public, and the scientific and engineering communities. The Council is administered jointly
by both Academies and the Institute of Medicine. Dr. Frank Press and Dr. Robert M. White are chairman and vice-chairman,
respectively, of the National Research Council.
Support for this project was provided by the American Chemical Society, the American Institute of Chemical Engineers,
the Council for Chemical Research, Inc., the U.S. Department of' energy under Grant No. DE-FG01-85FE60847, the National
Bureau of Standards under Grant No. 50SBNBSC23, the National Science Foundation under Grant No. CBT-8419184, and
the Whitaker Foundation.
Library of Congress Cataloging-in-Publication Data
National Research Council (U.S.). Committee on Chemical Engineering
Frontiers: Research Needs and Opportunities.
Frontiers in chemical engineering: research needs and
opportunities/Committee on Chemical Engineering Frontiers
Research Needs and Opportunities, Board on Chemical Sciences and
Technology, Commission on Physical Sciences, Mathematics, and
Resources, National Research Council.
p. cm.
Bibliography: p.
Includes index.
ISBN 0-309-03793-X (paper); ISBN 0-309-03836-7 (cloth)
1. Chemical engineering Research United States. I. Title.
TP171.N37 1988
620' .0072-dc 19
88-4120
CIP
(Rev.)
No part of this book may be reproduced by any mechanical, photographic, or electronic process, or in the form of a
phonographic recording, nor may it be stored in a retrieval system, transmitted, or otherwise copied for public or private
use without written permission from the publisher, except for the purposes of official use by the U.S. government.
Printed in the United States of America
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Pane! on Energy en cl natural Resources Processing
KEITH McHENRY (Chairman), Amoco Oil
Company
LESLIE BURRIS, Argonne National
Laboratory
ELTON J. CAIRNS, Lawrence Berkeley
Laboratory
NOEL JARRETT, Alcoa Laboratories
FREDERIC LEDER, Dowell Schlumberger
JOHN SHINN, Chevron Research Company
REUEL SHINNAR, City College of New York
PAUL B. WEISZ, University of Pennsylvania
Pane! on Er~nmental ProtecI;~n
Safely, and Hazardous Materials
ADEL SAROFIM (Chairman), Massachusetts
Institute of Technology
SIMON L. GOREN, University of California,
Berkeley
GREGORY J. MACRAE, Carnegie Mellon
University
THOMAS W. PETERSON, University of
Arizona
WILLIAM RODGERS, Oak Ridge National
Laboratory
GARY VEURINK, Dow Chemical Company
RAY WITTER, Monsanto Corporation
Pane! on Compeller Ass~si;ed Process
en c! Con1tro! 3~ng~eer~ng
ARTHUR W. WESTERBERG (Chairman),
Carnegie Mellon University
HENRY CHIEN, Monsanto Corporation
JAMES M. DOUGLAS, University of
Massachusetts
BRUCE A. FINLAYSON, University of
Washington
ROLAND KEUNINGS, University of
California, Berkeley
~' on ~a;~ a~d 4~$~'~i
ALEXIS T. BELL (Chairman), University of
California, Berkeley
RICHARD C. ALKIRE, University of Illinois
JOHN C. BERG, University of Washington
L. LOUIS HEGEDUS, W. R. Grace and
Company
ROBERT JANSSON, Monsanto Corporation
MANFRED MORARI, California Institute of
Technology
JEFFREY J. SIIROLA, Eastman Kodak
Company
WILLIAM SILLIMAN, Exxon Production
Research Company
,?- ~ ~ ~ ,= ~= rim. ~ ~
~ ~ 3, ~ j~ ~L ~ % ~
KLAVS F. JENSEN, University of Minnesota
JAMES R. KATZER, Mobil Research and
Development Company
LEIGH E. NELSON, Minnesota Mining and
Manufacturing Company
LANNY D. SCHMIDT, University of
Minnesota
~ ·/
OCR for page R4
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I' ~ mu= ~ ma; ~ a' Alit
If
EDWARD A. MASON (~Co-Chairman), Amoco
Corporation
GEORGE M. WHITESIDES (Co-Chairman),
Harvard University
NEAL R. AMUNDSON, University of Houston
JOHN I. BRAUMAN, Stanford University
GARY FELSENFELD, National Institutes of
Health
WILLIAM A. GODDARD III, California
Institute of Technology
JEANETTE G. GRASSELLI, BP America
MICHAEL L. GROSS, University of Nebraska
RALPH HIRSCHMANN, University of
Pennsylvania
ROBERT L. LETSINGER, Northwestern
University
JAMES F. MATHIS, Exxon Chemical
Company
GEORGE C. PIMENTEL, University of
California, Berkeley
JOHN A. QUINN, University of Pennsylvania
STUART A. RICE, University of Chicago
FREDERIC M. RICHARDS, Yale University
ROGER A. SCHMITZ, University of Notre
Dame
L. E. SCRIVEN, University of Minnesota
DAVID P. SHEETZ, Dow Chemical USA
LEO J. THOMAS, JR., Eastman Kodak
Company
NICHOLAS J. TURRO, Columbia University
MARK S. WRIGHTON, Massachusetts Institute
of Technology
ROBERT M. SIMON, Staff Director
WILLIAM SPINDEL, Special Staff Adviser
PEGGY J. POSEY, Staff Associate
LYNN E. DUFF, Financial Assistant
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i@ OH Skycap Eng~ee-~ing I:
Reseal c~ Nachos a~d We
NEAL R. AMUNDSON (Chairman), University
of Houston
EDWARD A. MASON (Vice-Chairman),
Amoco Corporation
JAMES WEI (Vice-Chairman), Massachusetts
Institute of Technology
MICHAEL L. BARRY, Vitelic Corporation
ALEXIS T. BELL, University of California,
Berkeley
KENNETH B. BISCHOFF, University of
Delaware
HERBERT D. DOAN, Doan Associates
ELISABETH M. DRAKE, Arthur D. Little,
Inc.
SERGE GRATCH, Ford Motor Company
(retired)
HUGH D. GUTHRIE, Morgantown Energy
Technology Center, DOE
ARTHUR E. HUMPHREY, Lehigh University
SHELDON E. ISAKOFF, E.I. du Pont de
Nemours and Company, Inc.
JAMES LAGO, Merck and Company (retired)
KEITH W. MCHENRY, JR., Amoco Oil
Company
SEYMOUR L. MEISEL, Mobil Research and
Development Company (retired)
ARTHUR B. METZNER, University of
Delaware
ALAN S. MICHAELS, North Carolina State
University
JOHN P. MULRONEY, Rohm and Haas
Company
LEIGH E. NELSON, Minnesota Mining and
Manufacturing Co., Inc.
· · -
JOHN A. QUINN, University of Pennsylvania
KENNETH J. RICHARDS, Kerr-McGee
Corporation
JOHN P. SACHS, Horsehead Industries, Inc.
ADEL F. SAROFIM, Massachusetts Institute
of Technology
ROBERT S. SCHECHTER, University of
Texas, Austin
WILLIAM R. SCHOWALTER, Princeton
University
L. E. SCRIVEN, University of Minnesota
JOHN H. SEINFELD, California Institute of
Technology
JOHN H. SINFELT, Exxon Research and
Engineering Company
LARRY F. THOMPSON, AT&T Bell
Laboratories
KLAUS D. TIMMERHAUS, University of
Colorado
ALFRED E. WECHSLER, Arthur D. Little,
Inc.
ARTHUR W. WESTERBERG, Carnegie-Mellon
University
ROBERT M. SIMON, Project Director
ROBERT M. JOYCE, Editorial Consultant
NANCY WINCHESTER, Editor
ROSEANNE PRICE, Editor
LYNN E. DUFF, Financial Assistant
MONALISA R. BRUCE, Administrative
Secretary
OCR for page R6
Panels of Ale Cornmit'ree
Pane! on Biochemical and Biomedical Engineering
ARTHUR E. HUMPHREY (Chairman), Lehigh
University
KENNETH B. BISCHOFF, University of
Delaware
CHARLES BOTTOMLEY, E.I. du Pont de
Nemours and Company, Inc.
STUART E. BUILDER, Genentech, Inc.
ROBERT L. DEDRICK, National Institutes of
Health
MITCHELL LITT, University of Pennsylvania
ALAN S. MICHAELS, North Carolina State
University
FRED PALENSKY, Minnesota Mining and
Manufacturing Co., Inc.
Pane! on Elec1;~or~ic, Photonic, and!
RCrOfdiOg Aha1;er~is and Devices
LARRY F. THOMPSON (Chairman), AT&T
Bell Laboratories
LEE F. BLYLER, AT&T Bell Laboratories
JAMES ECONOMY, IBM Almaden Research
Center
DENNIS W. HESS, University of California
Berkeley
RICHARD POLLARD, University of Houston
T. W. RUSSELL FRASER, University of
Delaware
MICHAEL SHEPTAK, Ampex Corporation
JPar~l=~ O= Aclvanc~c! Mi~Or~ al S
ARTHUR B. METZNER (Chairman),
University of Delaware
FRANK BATES, AT&T Bell Laboratories
C. F. CHANG, Union Carbide Corporation
F. NEIL COGSWELL, Imperial Chemical
Industries
WILLIAM W. GRAESSLEY, Princeton
University
By
FRANK KELLEY, University of Akron
JOHN B. WACHTMAN, JR., Rutgers
University
IOANNIS V. YANNAS, Massachusetts
Institute of Technology
OCR for page R7
Comm~ss~n Art Physical Sciences'
mat~mat~cs' and Resources
NORMAN HACKERMAN (~Chairman), Robert
A. Welch Foundation
GEORGE F. CARRIER, Harvard University
DEAN E. EASTMAN, IBM Corporation
MARYE ANN FOX, University of Texas,
Austin
GERHART FRIEDLANDER, Brookhaven
National Laboratory
LAWRENCE W. FUNKHOUSER, Chevron
Corporation (retired)
PHILLIP A. GRIFFITHS, Duke University
J. ROSS MacDONALD, The University of
North Carolina at Chapel Hill
CHARLES J. MANKIN, The University of
Oklahoma
PERRY L. McCARTY, Stanford University
JACK E. OLIVER, Cornell University
JEREMIAH P. OSTRIKER, Princeton
University Observatory
WILLIAM D. PHILLIPS, Washington
University
DENIS J. PRAGER, MacArthur Foundation
DAVID M. RAUP, University of Chicago
RICHARD J. REED, University of Washington
ROBERT E. SIEVERS, University of Colorado
LARRY L. SMARR, University of Illinois
EDWARD C. STONE, JR., California Institute
of Technology
KARL K. TUREKIAN, Yale University
GEORGE W. WETHERILL, Carnegie
Institution of Washington
IRVING WLADAWSKY-BERGER, IBM
Corporation
RAPHAEL G. KASPER, Executive Director
LAWRENCE E. McCRAY, Associate Executive
Director
OCR for page R8