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Clearing the Smoke: Assessing the Science Base for Tobacco Harm Reduction
TABLE 10–2 Some Typical SS/MS Yield Ratios for Plain Cigarettes
Substance
MS Yield
SS/MS
Small Molecules
Carbonyl sulfide
18–42 µg
0.03–0.1
HCN
160–500 µg
0.06–0.5
CO
10–23 mg
2.5–4.7
Hydrazine
20–43 µg
3
Methane
600–1000 µg
3.1–4.8
Acetylene
20–40 µg
0.8–2.5
Nitrogen oxides
100–600 µg
4–13
CO2
20–50 mg
8–11
H2 O (gas phase)
3–14 mg
24–30
NH3
50–130 µg
40–170
N2 (generated)
<10 µg
>270
Neutral Heteroatom Organics
Acetonitrile
50–130 µg
40–170
Benzonitrile
5–6 µg
7–10
Acetamide
70–100 µg
0.8–1.7
Methyl chloride
150–600 µg
1.7–3.3
Aldehydes, Ketones, Alcohols
Acetaldehyde
0.5–1.2 mg
1.4
Propionaldehyde
175–250 µg
2.4–2.8
Acetone
100–250 µg
2–5
Acrolein
60–100 µg
8–15
2-Butanone
~30 µg
2.9–4.3
2-Furaldehyde
15–43 µg
4.9–7.4
Furfuryl alcohol
18–65 µg
3.0–4.8
Cyclotenea
3–5 µg
6–10
Pyranoneb
13–150 µg
0.1–1.2
Phytosterols
β-Sitosterol
59 µg
0.5
Campesterol
43 µg
0.6
Cholesterol
22 µg
0.9
Phenols
Phenol
60–140 µg
1.6–3.0
Cresols (o-,m-,p-)
11–37 µg
1.0–1.4
Catechol
100–360 µg
0.6–0.9
Hydroquinone
110–300 µg
0.7–1.0
Acids
Formic acid
210–490 µg
1.4–1.6
Acetic acid
270–810 µg
1.9–3.9
3-Methylvaleric acid
20–60 µg
0.8–1.5