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Carbon Management: Implications for R & D in the Chemical Sciences and Technology (A Workshop Report to the Chemical Sciences Roundtable) (2001)
Commission on Physical Sciences, Mathematics, and Applications (CPSMA)

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. "7. Renewable Energy: Generation, Storage, and Utilization." Carbon Management: Implications for R & D in the Chemical Sciences and Technology (A Workshop Report to the Chemical Sciences Roundtable). Washington, DC: The National Academies Press, 2001.

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Page 126

a really well understood effect, but under light soaking, the system loses some of its efficiency in the first six months of operation.

So, the films start out at 15% and then in six months they drop down to 10 or 12%. This particular degradation mechanism is somewhat understood, but how to control it is not.

Dave Cole: Is moisture an issue in temperate zones where it is not always dry? Is water or humidity a factor?

John Turner: Water is not an issue with current sealing technologies for single-crystal silicon cells.

Dave Cole: Is that true for the amorphous silica also?

John Turner: It is the same for amorphous silica. Amorphous silicon uses the same sealing technique.

Dave Cole: What do you mean by “sealing technique”?

John Turner: Typically, the silicon is deposited either on glass or on stainless steel and sealed with a plastic. The plastic is called ethoxybenzoic acid (EBA), but I've forgotten what that means now. It is a cover that seals everything up. It lasts about 20 years. The degradation of EBA is really what limits the lifetime of silicon solar cells.

David Keith, Carnegie Mellon: I think I heard you say that the use of water in electrolysis to make hydrogen would lead to some water shortages. Is that correct?

John Turner: It is going to be an issue if you only have water—

David Keith: I don't get it. I mean about a meter of water a year falls in the typical temperate zones. That means on each hectare you get 104 square cubic meters of water per year.

John Turner: Yes.

David Keith: Yet the amount of water that you need to make hydrogen, assuming you—

John Turner: Pretty small.

David Keith: It is of order 10 cubic meters. So, there is a difference of 103.

John Turner: Right, but it is the culmination that makes the difference. Water is used for food, people and industry. If you add hydrogen production to that, there may be a problem. If you take it by itself, you are absolutely right.

David Keith: It is down by three orders of magnitude.

John Turner: It is going to be an issue.

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