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TABLE 9–1 Physical and Chemical Properties for Sulfur Dioxide

Characteristic

Value

Molecular formula

SO2

Synonyms

Sulfurous anhydride, sulfurous oxide, sulfur oxide, sulfurous acid anhydride

Molecular weight

64.07

CAS number

7446–09–5

Solubility

Soluble in water, alcohol, acetic acid, sulfuric acid, ether, and chloroform

Density

2.811 g/L

Vapor pressure

3×10–3 mm Hg at 25°C

Saturated vapor pressure

0.47 lb/ft3 at 15°C

Melting point

–72°C

Boiling point

–10°C

Conversion factors in air, 1 atm

1 ppm=2.6 mg/m3

1 mg/m3=0.38ppm

Abbreviation: CAS, Chemical Abstracts Service.

Source: NRC (1984); Budavari (1989); ACGIH (1994); ATSDR (1998); HSDB (2000).

Sulfur dioxide is formed when materials containing sulfur are burned. It is a primary air pollutant emitted by smelters and electrical power plants that burn coal or oil. Sulfur dioxide is found at concentrations of 1–10 parts per billion (ppb) in clean ambient air, and at 20–200 ppb in polluted air (Seinfeld 1986). Sulfur dioxide also is used in treating wood pulp for paper manufacturing; in ore and metal refining; in extraction of lubricating oils; as a bleaching, disinfecting, and fumigating agent; as a food additive and preservative; and as a reducing agent. Sulfur dioxide is a precursor to acid sulfates, which generally are more toxic; therefore, recent research has focused on those compounds (Costa and Amdur 1996).

TOXICOKINETIC CONSIDERATIONS

Absorption

Sulfur dioxide is primarily an upper airway and eye irritant. In the airways, it produces bronchoconstriction and mucous secretion. Because of its high water



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