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Summary of the Workshop on Structural Nanomaterials
Ganesh Skandan of Nanopowder Enterprises followed Professor Weertman with his talk “Synthesis and Processing of Nanopowders: Overcoming Technical and Commercial Challenges.” He then discussed several applications of nanopowders and their characterization:
The performance of Li-ion batteries is limited by the electrodes. With the use of nanopowders of lithiated V2O5, MnO2, tin alloys, and Li4Ti5O12, Li ion diffusion is faster and a 30 to 60 percent improvement in capacity is obtained.
The basic science issues of cyclability, mixing, and electrolyte-electrode interface need to be investigated.
The property enhancement in electrodes needs to be transferred to cells and then to batteries, which is a major leap. Dr. Skandan noted that Yt+3 ions are potentially superior to Li+1 ions. However, he felt that it would take 12 years to bring Yt-ion technology to market because it requires much more testing.
Thermal spray powders for use by the U.S. Navy must work in the Navy’s spray guns. Otherwise they will not be considered. In the case of WC/Co powders, a mixture of coarse and nanosize powders gives better results. Further, the Co content can be reduced. Adding Cr to the powders increases corrosion resistance, a factor important to the Navy. Dr. Skandan’s company can produce tons of the powder. The challenge is cost.
There is no commercially available tool that can characterize all the relevant features of a nanopowder. Existing methods are fooled by agglomeration in the powders.
The size distribution of powders can be completely characterized by small-angle x-ray scattering (SAXS) and ultra-SAXS.
The key is to develop a SAXS system that can be used by an engineer/scientist not skilled in SAXS.