TABLE 4-1 Some Key Characteristics and Features of Microwave Processing
|
Characteristic |
Feature |
Benefits (over conventional heating) |
Disadvantages |
|
1. Penetrating radiation, direct bulk heating |
• Materials heat internally • Reversed thermal gradients (ΔT) • Lower surface temperatures • Instantaneous power/temperature response • Low thermal mass • Applicator can be remote from power source |
• Potential to heat large sections uniformly • ΔT favors chemical vapor infiltration; matrix infiltration • Reduced skin effect on drying • Removal of binders & gases without cracking • Improved product quality and yields • Materials & composite synthesis • Automation, precise temp. control • Rapid response to power level; pulsed power • Heat in clean environment • Materials synthesis • See differential coupling |
• M/W transparent materials difficult to heat • Hot spots, cracking • Large ΔT in low thermal conductivity materials, and nonuniform heating • Controlling internal temperature • Arcing, plasmas • Require new equipment designs special reaction vessels |
|
2. Field distributions can be controlled |
• High energy concentration • Optimize power level versus time • mm-waves can be focused or defocused, rastered as desired |
• Precise heating of selected regions (brazing, welding, plasma generation, fiber drawing) • Process automation, flexibility, energy saving • Synthesis of materials, composites, powders, coatings |
• Equipment more costly and complex • Requires specialized equipment |
|
3. Dielectric losses accelerate rapidly above Tcnt |
• Very rapid heating |
• Rapid processing (2-1000x factor) • Heat materials > 2000 ºC • Capable to heat M/W transparent materials > Tcnt |
• Hot spots, arcing • Nonuniform temperature • Control of thermal runaway |
|
4. Differential coupling of materials |
• Selective heating of internal or surface phases, additives or constituents |
• Heating of M/W transparent, materials via additives, fugitive phases, etc. • Hybrid heating (active containers) • Materials synthesis • Selective zone heating (joining, brazing, sealing) • Controlled chemical reactions, oxidation, reduction; use of M/W transparent containers • Drying, curing, annealing; matrix infiltration |
• Reactions with unwanted impurities • Contamination with insulation or other phases |
|
5. Self-limiting |
• Selective heating ceases (self regulating) after certain processes have been completed |
• Below critical temperature, drying & curing are self-regulating • Completion of certain phase changes is self-regulating |
• Undesired decoupling during heating in certain products • Difficult to maintain temp. |