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Index
A
Acrylonitrile butadiene styrene (ABS), 27, 68, 84
Adenosinetriphosphate (ATP), 43
Adhesives, 65, 66, 73, 75, 82-83, 102
Aerosols, 38
Agarose, 38
Agriculture, 23, 34, 114
Aircraft and aviation applications, 5, 9, 16, 17, 23, 27, 29, 65, 68, 75, 87, 88, 105, 153
military, 28, 29-30, 31, 88, 101
Albumin, 35
Aliphatic polyamides, 51, 93
Alloys, see Blends and alloys
Amino acids, 32, 42-43, 44, 132
Amorphous polymers, 106, 155
Amphibious vehicles, 30, 31
Amplifiers, 58, 59
Antibodies, 38, 43, 53
Anticancer drugs, 38, 39
Antigens, 38, 43
Antioxidants, 67, 107
Antistatic agents, 67
Aqueous dispersion, 110, 111
Aramids, 90
Aryl-phosphine-oxide materials, 76
Atomic force microscope (AFM), 150
Automated clinical analyzer (ACA) systems, 37
Automobiles, 5, 9, 23, 26-27, 28, 65, 68, 85, 86, 105
recycling, 25, 27
B
Barrier polymers, 92-94
Basic and long-term research, 3, 4, 12, 13, 16
Batteries, 28, 52, 63, 102
Benzocyclobutene (BCB), 49, 75
Biocatalysis, 131-132, 138
Biocompatibility, 33-34, 39, 102
Biocomposites, 44-45
Biodegradation, 25, 39, 83, 114, 132
Bioelastomers, 44
Biological polymers, 1-2, 6, 42-45, 159
characterization of, 140, 141, 150-152
collaborative and interdisciplinary research, 4, 7, 45-46
Biological systems and processes, 2, 6, 32-33, 43, 136-137
see also Biological polymers
Biomimetic materials, 35
Biopolymers, see Biological polymers
Biotechnology, 2, 32, 34, 37, 43, 53, 96, 98, 153
Bismaleimides, 75, 82
Blends and alloys, 67, 68, 72, 83-87, 105, 114, 157-158
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Block copolymers, 38, 42, 76, 120, 123-125, 158
Blood, 33, 34, 35, 53, 63
Blow molding, 72, 105, 107
Bottles, 23, 25, 67, 72, 93-94, 114
C
Capillary zone electrophoresis, 150
Carbon-based polymers, see Organic polymers
Carbon fibers, 17, 30
Catalysts and catalysis, 2, 6, 72, 104, 123
biological, 131-132, 138
Cellulose, 2, 79, 96, 108
CERAMERS, 103
Ceramics, 7, 36, 54, 65, 103, 104
Chain architecture, 2, 9, 42, 43, 44, 117-123, 138
isomerism, 120-123
length, 119-121
sequence control, 120
topology, 117
Characterization of polymers, 6, 72, 73, 139, 152-153
biopolymers, 140, 141, 150-152
microscopy, 2, 6, 43, 143, 146-148
molecular, 139-144
solid-state structure and properties, 140, 141, 146-148
solutions, melts, and elastomers, 140, 141, 144-146
surfaces and interfaces, 140, 141, 148-150
CHEMFETS, 53
Chemical structures and processes, 2, 32, 66, 67, 114, 115
adhesives, 82-83
biopolymers, 42, 44, 45
sensor devices, 52-54
Chlorofluorocarbons (CFCs), 24, 28
Chromatography, 141-142, 150
Chromophores, 59
Clothing, 2, 9, 23, 65, 114
protective, 29, 90, 109
Coatings, 53, 65, 73, 92, 98-100, 102, 104, 105, 110, 111
Collaborative research, 3-4, 5-6, 7
see also Interdisciplinary studies and research
Collagen, 32-33, 42, 78
Commodity polymers, 3, 5, 46, 65, 68, 79, 113
Communications technologies, 2, 5, 32, 46-47, 61, 63, 107
see also terms listed under Electronics
Compact disk (CD) technology, 57-58, 63, 106
Composites, 17, 27, 28, 30, 36, 48, 54, 65, 67, 75, 90, 104
structural, 87-89, 94
Computation and simulation, 2, 6, 142, 152, 153-155, 162-168
Concrete-plastic, 27
Conducting polymers and synthetic metals, 50-52, 63, 91
Conjugated polymers, 127
Connective tissues, 32-33, 34
Construction, see Housing and construction materials
Contact lenses, 33, 37, 73, 102
Containers, see Packaging and containers
Contraceptive implants, 38
Controlled-release materials, 53, 92
drugs, 38-41, 95, 104, 109
Coordination catalysis, 121
Corrosion-resistance, 30-31
Cross-linking, 37, 44, 67, 127
Crystallinity, 44, 67, 80, 156
see also Liquid crystalline polymers
Crystallography, 43, 151
Cuprophan, 35
Curriculum development and guidelines, 19, 21
Cyanates, 75
D
Defense, see Military and defense applications
Degradation of waste materials, 23, 24, 25
research needs, 7, 25-26
Dental applications, 33, 35-36
Depth profiling, 148-149
Desalinization of water, 95, 96
Dextrans, 38
Dextrin, 82-83
Diagnostic applications, 37-38
Dielectrics, 46, 47-50, 62
printed circuit boards, 46, 47, 48
Diffusion-controlled systems, 38
Dimethacrylates, 36
Diodes, see Light-emitting diodes
Dispersion processing, 110-111
Disposable diagnostic kits, 37-38
Disposal of materials 3, 6-7, 10, 23, 24, 25, 139
see also Recycling
Distribution and movement of materials, 3, 10
DNA (deoxyribonucleic acid), 2, 32, 42, 43, 150
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Drugs, 43, 102
controlled-release, 38-41, 95, 104, 109
Dyes, 53, 104
E
Education in polymer science, 4, 18-22, 83
see also Universities
Elastin, 33, 78
Elastomers, 28, 67, 73, 76-78, 82, 85, 102
see also Bioelastomers;
Fluoroelastomers
Electronics, 2, 4, 5, 7, 32, 52
see also Compact disk technology;
Conducting polymers and synthetic metals;
Dielectrics;
Electrophotography;
Integrated circuits;
Light-emitting diodes;
Multichip modules;
Photonics;
Printed circuit boards;
Resist materials;
Semiconductors;
Sensors;
Silicon chips
Electron spin resonance, 43
Electron tomography, 146-147
Electrophotography, 59-61, 63
Electrotransport systems, 39
Emulsion polymerization, 111
End-group structure, 123-125
Energy consumption and savings, 2, 5, 10, 23, 24, 26-29, 63, 114
Energy devices and equipment, 29
Engineering plastics, 3, 5, 32, 65, 68-69, 114
Environmental applications and issues, 3, 7, 10, 22-26, 95, 109,111, 113
government policies, 6, 7, 99-100
research needs, 6-7, 114, 115
synthesis control, 6, 138-139
see also Incineration;
Recycling
Enzymes, 32, 34, 53, 131
Epoxies, 10, 47, 48, 73, 82
Ethylene-propylene-diene monomer (EPDM) rubbers, 78
Exports, see Trade and trade balances
Extrusion processes, 67, 72, 105, 107, 112
F
Fabrics, see Clothing;
Textiles and fabrics
Factory-built structures, see Prefabricated structures
Federal research funding, 3, 4, 10
see also National laboratories
Ferroelectric polymers, 54, 104
Fiberglass, 45, 48
Fiber optics, 53, 58, 63, 107
Fibers, 5, 48, 65, 66, 67, 72, 78-81, 90, 105
environmental issues, 23, 79
international competitiveness, 17
reinforcement, 88-89, 105
see also Textiles and fabrics
Fillers, 67, 78, 107
Films, 6, 17, 51, 53, 54, 59, 65, 67, 72, 78, 92, 103, 105, 107,159
see also Barrier polymers
Flammability resistance, 75-76, 107
Flocculants, 111
Fluorescent imaging, 144
Fluoroelastomers, 17, 78
Fluoropolymers, 33, 46, 47, 54, 102, 130
"Folding problem," 152
Force-field simulation, 163-165
Foreign corporations, 16-17
Foreign expenditures for research, 3, 12
Fracture mechanics, 114
Free radical polymerization, 121, 122
Fuel cells, 28
Funding for research and development, 1, 2, 3-4, 5, 6, 11-16
academic, 10, 12, 14
government sources, 3, 5, 8, 10, 11
industry sources, 3, 4, 5, 10, 11, 12-16, 57
and international competitiveness, 3, 10, 12, 16, 17
G
Gas separation, 95, 96
Gel electrophoresis, 150
Gel spinning, 72
Gelation, 73
Genetic engineering, 34, 120, 132
Geometrical isomers, 120-121
Glass and glass fibers, 17, 23, 37, 47, 48, 67, 75, 89, 104
see also Fiber optics
Global competition, see International competitiveness
Glucose sensors, 53, 54, 63
Government policies and legislation, 3, 5, 10
environmental, 6, 7, 99-100
Government research support, 3, 5, 8, 10, 11
see also National laboratories
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H
Health applications, see Medical applications
High-density polyethylene (HDPE), 70, 72, 108
Holography, 61-62, 63
Homopolymers, 42
Household furnishings, 26, 27, 65, 105
Housing and construction materials, 5, 10, 26, 27, 88-89
see also Household furnishings
Hydrocarbons, 10, 82, 121
Hydrogel, 37
Hydrophilic coatings, 35, 102
Hydrophones, 54
Hyperbranched macromolecules, 117
I
Implants and prostheses, 3, 9, 33, 34-37, 102
for controlled drug delivery, 38, 39, 63
Imports, see Trade and trade balances
Incineration, 7, 25, 94, 114
Industry
collaboration with universities, 4, 5, 12, 14, 22
infrastructure, 3, 10
research facilities and groups, 3, 5, 10, 12, 16
research support and priorities, 3, 4, 5, 10, 11, 12-16, 57
revenues and sales, 5, 15, 16
see also Manufacturing and production technologies;
Processing methods
Informational polymers, 33, 42-43
Information technology applications, 5, 32, 46-47, 63, 153
see also Compact disk technology;
Conducting polymers and synthetic metals;
Dielectrics;
Electronics;
Electrophotography;
Holography;
Light-emitting diodes;
Photonics;
Resist materials;
Sensors
Injection molding, 105-107, 137
Inorganic polymers, 2, 9, 100-104, 133-137
network-forming, 135-136
Insulators, 29, 46, 48, 49-50, 65, 102
Insulin pumps, 54, 63
Integrated circuits, 46, 63
Interdisciplinary studies and research, 6, 32, 138, 152-153
see also Collaborative research
International competitiveness, 1, 2-3, 10, 16-17, 63, 65, 153
and research funding, 3, 10, 12, 16, 17
Intrinsically conducting polymers (ICPs), 50-51
K
Kevlar, 10, 29, 89, 108, 109, 161
L
Laboratories, see National laboratories
Landfills, 7, 23, 114
Lasers, 57, 61, 104, 111, 146
Lateral force microscope (LFM), 150
Light-emitting diodes (LEDs), 3, 59, 61, 63
Linear low-density polyethylene (LLDPE), 72, 117
Liquid crystalline polymers, 27, 45, 63, 67, 77, 79, 80, 89-92, 104
processing, 105, 106, 110
theory, 156-157
Lithography, 49, 59, 63
see also Pattern formation;
Photolithography;
Resist materials
Long-term research, see Basic and long-term research
Low-density polyethylene (LDPE), 70, 71, 72
Lubricants, 28, 67, 107
Lyotropic polymers, 89-90
M
Manufacturing and production technologies, 3, 5, 6, 10, 65-66, 115
environmental and health issues, 3, 7, 10, 23, 24
inorganic polymers, 100-104
minimization of waste, 7, 114
structural polymers, 66-92
see also Processing methods
Mechanical properties and processes, 6, 46, 51, 66, 114, 147, 161-162
biopolymers, 42, 44
blends and alloys, 84-86
elastomers, 77-78
failure modes, 6, 28, 161
Medical applications, 2, 4, 5, 6, 33-34, 35, 37, 39, 54, 63, 102, 104, 114
see also Dental applications;
Diagnostic
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applications;
Drugs;
Implants and prostheses
Melt processing, 67, 81, 105
extrusion, 67, 72, 105, 107, 112
molding, 105-107
solid-state forming, 108
Membranes, 38, 92, 94-98, 102, 104
international competitiveness, 95
Merrifield-type synthesis, 43
Metallocenes, 72
Metals, 7, 23, 36, 65
see also Conducting polymers and synthetic metals
Microbial synthesis, 131-132
Microelectronics and micromachinery, 54, 55, 63
Microporous materials, 35, 40, 95, 104
Microspheres, 38
Military and defense applications, 2, 5, 10, 29-31, 105
aircraft, 29-30, 31, 88, 101
vehicles, 30, 88
Modeling, 6, 73, 153-155, 162-168
processing methods, 6, 105, 110, 112-113, 115, 153
Molding and molding materials, 17, 67, 72, 105-107, 112, 137
Molecular recognition, 6, 43
Molecular structures and processes, 1, 6, 9-10, 33, 42, 43, 65, 66, 72
and processing, 106, 107, 109, 112-113
characterization of, 139-144
elastomers, 78
weight control, 119, 120
see also Chain architecture;
End-group structures
Monomers, 2, 9, 39, 42, 49, 62, 137
Monte Carlo statistical methods, 165-166
Multichip modules (MCMs), 47, 49
N
National defense, see Military and defense applications
National laboratories, 3, 5, 10, 152
Natural polymers, see Biological polymers
Naval structures, 29, 30-31
Near-field scanning optical microscopy (NSOM), 146
Nematogenic polymers, 90-91
Neuronal tissue, 34
Neutron scattering, 144
NICALON, 103
Nitrile, 82
Nitrosoureas, 39
NOMEX, 108
Nonaqueous dispersion (NAD), 110, 111
Nondestructive testing, 61, 83
Nonlinear polymers, 58-59, 104
Nonprofit organizations
research support, 12, 14
Novolac, 47
Nuclear magnetic resonance (NMR) imaging, 73, 142-143, 150
Nucleating agents, 67
Nylon, 2, 10, 68, 79, 93, 100
Nylon acrylamide, 38
O
Ocular materials and implants, 33, 34, 37, 38
Oligomers, 68, 69, 114, 119
Optical technologies, 46, 58-59, 91, 104
see also Compact disk technology;
Electrophotography;
Fiber optics;
Holography;
Photonics
''Optical tweezers," 43
Organic polymers, 2, 9, 23, 47, 50-51, 100
Organometallic macromolecules, 133, 134, 136
ORMOCERS, 103
P
Packaging and containers, 5, 24, 27, 33, 46, 65, 67-68, 72, 84, 92-94, 114, 132
Paint, see Coatings
Pattern formation, 55-56
Pervaporation, 95, 96-97
Petroleum derivatives, 9, 23, 65, 114
Phosphorylcholines, 35
Photocuring, 35, 36
Photodegradation, 25
Photoduplication, 59-61
Photolithography, 46, 47, 53
Photonics, 58-59, 63
Photoreceptors, 60, 61
Piezoelectric materials, 46, 54, 121
Plasticizers, 35, 67, 107
Plastics, 10, 16, 66, 67-76
environmental issues, 23, 24
Plexiglas, 10, 36, 55
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Poled polymeric systems, 59
Pollution, see Disposal of materials;
Environmental applications and issues
Polyacetals, 50, 51, 68, 75, 127
Polyacrylamide, 30, 111
Polyacrylonitrile, 93, 108
Polyamides, 33, 51, 69, 82, 85, 100
Polyanhydrides, 38
Polyaniline, 51-52, 59, 127
Polyaryl sulfones, 106
Polybenzimidazoles, 108
Polyborazines, 136
Polybutadiene, 121, 122
Poly(butylene terephthalate), 27, 85
Polycarbonate, 27, 33, 57-58, 67, 68, 69, 84, 85, 96, 106
Polycarbosilanes, 136
Polydimethylsiloxane (PDMS), 96, 102
Polyesters, 25, 33, 47, 67-68, 73, 75, 79, 82, 84, 89, 94, 100, 109
Polyetherimides, 68, 106
Polyetherketones, 69, 75, 130
Poly(ether urethanes), 38
Polyethylene, 2, 10, 46, 51, 67, 69-70, 82, 84, 93, 100, 125, 130
medical applications, 33, 35, 37
Poly(ethylene oxide), 100
Poly(ethylene terephthalate) (PET), 27, 35, 59, 67, 68, 94, 107,114
Polyfuran, 51
Polyglycols, 123, 125
Poly-HEMA hydrogel, 37
Polyheteroaromatic vinylenes, 51
Polyimides, 49, 75, 82, 96, 130
Polymerase chain reaction (PCR), 150
Polymerization, development of new methods for, 132
Polymer Recycling Consortium, 25
Poly(methyl methacrylate) (PMMA), 35, 37, 55, 57, 86, 100, 103
Polynucleic acids, 43
Polyolefins, 70, 72, 79, 125
Polyols, 123-125
Polyoxymethylene, 100
Polyparaphenylene, 51, 127
Poly(paraphenylene terephthalamide), 109
Polypeptides, 32, 38, 43, 100, 120
Poly(phenylene oxide), 27, 84, 85
Poly(phenylene sulfide), 69, 75
Poly(phenylene vinylene) (PPV), 51, 52, 59, 127
Polyphosphazenes, 78, 102, 104, 133, 134
Polypropylene, 35, 67, 68, 82, 86, 93, 125, 130
Polypyrrole, 51, 52
Polysaccharides, 33, 42
Polysilanes, 102-103, 133, 134-135
Polysilazanes, 136
Polysiloxanes, 78, 100, 102, 104, 133, 135
Polystyrene, 38, 67, 76-77, 84, 85, 86, 100
Polysulfide elastomers, 35
Polysulfones, 68, 69, 130
Poly(tetrafluoroethylene), 35, 54, 110
Polythiophene, 51, 52, 127
Poly(trimethylsilyl propyne), 92
Polyurethanes, 33, 34, 35, 73, 124
Poly(vinyl acetate), 83, 121
Poly(vinyl alcohol), 92, 93
Poly(vinyl chloride), 25, 35, 67, 86, 93, 100, 121
Poly(vinylidene fluoride), 54, 121
Powder dispersion, 110-111
Precollege education, 21
Prefabricated structures, 26, 27
Pressure-sensitive adhesives, 82
Primary education, 21
Printed circuits boards (PCBs), 46, 47, 48
Processing methods, 18, 66, 91, 104-105
computer-assisted design, 6, 112
dispersion, 110-111
environmental issues, 7, 23, 109, 110
equipment, 3, 10, 17, 105
fibers, 80-81
films, membranes, and coatings, 92-100, 110
and international competition, 17
melt, 105-108
modeling, 6, 105, 110, 112-113, 115, 153
reactive, 137
research needs, 6, 72, 73, 75, 105-106, 110
solution, 108-110
Prostheses, see Implants and prostheses
Pumps, for controlled drug delivery, 38
R
Raman spectroscopy, 143-144
Rayon, 108
Reaction injection molding (RIM), 137
Recreational applications, 9, 31, 65
Recycling, 23, 24, 25, 67, 68, 94, 105, 113-114
research needs, 7, 113-114
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Regioisomerism, 120, 121
Resist materials, 54-57, 63, 121
Reverse osmosis, 95, 96
Rheology, 100, 106, 107, 112, 113, 115, 144
liquids, 160-161
Ribosome assemblies, 43
Ring-opening metathesis polymerization (ROMP), 69, 119, 125
RNA (ribonucleic acid), 33, 42, 43, 150
Robotics, 54, 55
Rotational molding, 72
Rotaxanes, 117
Rubber products, 5, 35, 65, 66, 75, 78, 82, 90, 111
see also Elastomers
S
Scanning electron microscopes (SEMs), 146, 147, 151
Semiconductors, 49, 50, 53-55, 56, 57
Sensors, 52-54, 63, 88, 104
Silane, 36
Silicate cement, 36
Silicon chips, 46, 47, 54-55
Silicones, 2, 9, 17, 34, 57, 82, 100, 101, 133
medical applications, 33, 34, 35
rubbers, 35
Simulation, see Computation and simulation;
Modeling
Skin grafts and replacement, 34, 102
Smart materials, 63, 88, 92
Sol-gel processing, 135-136
Solution processing, 108-110, 155
Spandex, 73
Specialty polymers, 2, 3, 5, 46-47, 57, 108
international competitiveness, 17, 65
Spectra, 29
Stabilizers, 67
Starch-based polymers, 2, 25-26, 83
Stealth design, 31, 88
Steel substitutes, 27, 28, 30, 88, 104, 109
Structural polymers, 5, 42, 66, 66-67, 114
composites, 87-89, 94
see also Adhesives;
Blends and alloys;
Elastomers;
Fibers;
Liquid crystalline polymers;
Plastics
Styrofoam, 10, 24
Surface forces apparatus (SFA), 149
Surfaces and interfaces, 60, 114, 158, 159
and biological processes, 34, 38
blends and alloys, 84-85
treatments, 35, 83
Surlyn, 37
Switches, 58, 59, 78, 105
Synthesis control and development, 6, 18, 116-117, 132-133, 138-139
biocatalysis, 131-132, 138
chain architecture, 117-123, 138
conjugated polymers, 127
end-group structure, 123-125
polymerization, 132
inorganic polymers, 133-137
reactive processing, 137
supramolecular chemistry, 137-138
surface modification, 129-131
thermal stability, 125, 127, 128
Synthetic rubber, see Elastomers
T
Tactile sensors, 54
TCNQ, 50
Teflon, 2, 10, 110
Telechelic polymers, 123-125
Textbook development, 19
Textiles and fabrics, 5, 10, 23, 67, 105
see also Clothing
Theory, 2, 6, 18, 153-155, 167-168
dynamics and properties, 159-162
elastomer properties, 77, 78
states of matter, 155-159
Thermal properties, 6, 47, 49, 51, 54, 108
of blends, 84, 86-87
stability, 125, 127, 128
Thermoplastics, 60, 65, 67-73, 105
Thermosets, 67, 73-76, 105
Thermotropic polymers, 89, 90, 106
Tires, 28, 65, 76, 109
Tissue engineering, 34, 104
Titansiloxane, 103
Top surface imaging, 56-57
Trade and trade balances, 2, 3, 5, 9, 16, 113
see also International competitiveness
Transdermal drug delivery, 38, 39, 40
Transmission electron microscope (TEM), 146
Transportation and transportation equipment, 2, 5, 10, 26-29
energy consumption, 23, 26-27
Transport kinetics, 53, 95, 96, 98
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U
Ultrasonic transducers, 54
Ultraviolet (UV) radiation and imaging, 46, 56, 60, 143
Undergraduate education, 18
Universities, 3, 4, 8, 10, 18-19
collaboration with industry, 4, 5, 12, 14, 22
faculty, 18-19, 21, 22
research budgets and funding, 10, 12, 14
V
Vascular grafts and prostheses, 33, 34, 35
Vinyl pyrrolidone, 37
Volatile organic compounds (VOCs), 98
Vulcanizates, 73
W
Water purification and desalinization, 95, 96, 111, 115
X
X-ray radiation and imaging, 56, 144-146, 147, 148, 150
Xanthum gum, 30
Z
Ziegler catalysts, 78
Representative terms from entire chapter:
processing methods