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OCR for page 81
Appendix A: Silicon as a High-Temperature Material
Silicon is the dominant semiconductor material in use
by the electronics industry today, but is generally not
thought of as a high-temperature semiconductor material.
Its comparatively narrow energy bandgap creates the
majority of problems during high-temperature operation
when attempting to use silicon material as a discrete
device or in integrated circuits for digital, analog, or
power applications. However, surveys of the literature
indicate that silicon bipolar and complementary metal-
oxide semiconductor (CMOS) analog and digital products
can function adequately beyond the MIL SPEC limit of
125 °C. Circuit and layout techniques can extend the
reliable temperature range of conventional bulk CMOS
and bipolar to at least 200 °C, while a combination of bi-
CMOS, conservative layout rules, supply voltage reduc-
tion, and scaling of transistor (channel) dimensions can
extend the range to 250 °C. The further addition of oxide-
isolated processes can extend silicon bipolar and CMOS
circuitry to 300 °C by reducing leakage currents, parasitic
capacitances, and threshold voltage-dependence on
temperature. General high-temperature issues for semicon-
ductors, which also pertain to silicon, are discussed in
Chapter 3. This appendix begins with a description of
high-temperature performance of several silicon technolo-
gies, then moves on to a consideration of oxide-isolation
processes that can extend the functional temperature range
of silicon circuits.
HIGH-TEMPERATI)RE OPERATION
OF SILICON CIRCUITS
Bipolar Analog Circuits
Historically, operational amplifiers have been the
most-studied bipolar analog integrated circuit. The
changes in bipolar component characteristics mentioned
81
above can be so great with respect to temperature that
conventional design methods cannot be used; in fact,
design compensation techniques may be only valid for
limited temperature ranges. Leakage currents must be
compensated for in all designs; for example, the base-
collector leakage current, ICbo, flows in the opposite
direction to the normal base current and can become
larger than the normal base current as operating tempera-
tures increase, reducing the base current necessary to
sustain collector current. Decreases in base-emitter
voltage, Vbe (less than 100 mV), can force devices to go
into saturation; current design must be used to compensate
for this unintentional saturation. In general, large changes
in parameters such as Vbe and diffused resistor values of
the base and collector cause problems in obtaining
controlled and constant circuit performance over wide
ranges (Beasom and Patterson, 1982~. These parameter
changes manifest themselves as failures due to degradation
in the input-offset voltage, VOS, the open-loop gain, and
the bias current.
Bipolar Digital Circuits
Commercial four-input standard and Schottky-clamped
TTL NAND gates were tested from 25-325 °C. The high-
temperature [allure modes of both TTL NAND gates were
identical. The functional failure mode was low output-high
voltage, Voh, and contributed to the collector-base leakage
current (from the phase splitter transistor) flowing through
the phase splitter collector resistor. The voltage drop
across the collector due to the excess leakage resulted in
a decrease in Voh. The power-supply currents for output-
high and output remained stable through 300 °C. Current-
sinking capability increased as the temperature was
increased due to the increasing gain of the current-sink
transistor. Current-sourcing capability was reduced due to
OCR for page 82
Materials for High-Temperature Semiconductor Devices
the increase in circuit resistance values (Prince et al.,
1980).
FET Analog Circuits
Design techniques for high-temperature analog CMOS
generally try to address the temperature dependence of
mobility, drain current, threshold voltage, and leakage
currents of MOS transistors as a first attempt to increase
the range of temperature operation. Observed effects in
analog CMOS circuits due to changes in transistor
parameters include: (1) a decrease in amplifier-gain
bandwidth product and gain, (2) an increase in amplifier
input-offset voltages, (3) bias point shifts, and (4) a de-
crease in sampling rate due to leaky switches.
For a simple two-stage CMOS operational amplifier,
design techniques have been used to allow the op amp to
function up to 250 °C. The most important design
technique used was to bias the two gain stages and the
output stage at their zero temperature coefficient (ZTC)
drain currents in the saturation region (e.g., ZTC is a
gate-bias voltage at which the drain current exhibits
minimum temperature sensitivity). The ZTC gate bias was
applied to the current source biasing each gain stage and
to the n-MOS of the output stage by using a voltage divid-
ing string composed of n- and p-MOSFETs. Leakage
currents were compensated for by cascading n- and p-
MOSFETs or by using compensation diodes. Cascading
was used in the voltage dividing string and the output
stage. Cascading of n- and p-MOSFETs to a common
circuit node allows the leakage currents from the drain to
body of the n-MOS and the source to body of the p-MOS
to cancel each other with appropriate selection of MOS-
feature sizes. For the differential input stage, a compensa-
tion diode can be placed at any node where the use of
cascaded MOS pairs is not possible; the diode can then be
used to shunt excess current to one of the power rails
(Shoucair, 19861.
Digital CMOS
General high-temperature effects observed for digital
CMOS include: (~) decreasing noise margins and (2)
decreasing switching speeds. CMOS type 4012 NAND
circuits were tested from 25-300 °C, with acceptable
performance noted to 270 °C. Leakage current on the p-
well-substrate junction was determined to limit circuit
82
functionality. The output-low voltage, VO', increased at
high temperatures due to the inability of the e-channel
transistors to sink the leakage currents generated at high
temperature. Change in threshold voltages also altered the
logic threshold of the voltage transfer characteristics
(Prince et al., 19801. Additional layout (e.g., guardrings
or larger n-MOS/p-MOS separation) or processing
techniques (e.g., epitaxial substrates or trenches) may be
required to suppress latchup at higher temperatures
(Estreich and Dutton, 1982~.
DIELECTRIC ISOLATION TECHNOLOGY
Leakage current in reverse-biased junctions is one of
the major problems with the operation of junction-based
devices and junction-isolated integrated circuits (ICs) at
high temperatures. In bulk CMOS, large junction areas
exist between the source, the drain, and the p-well, and
between the p-well and the substrate. For junction-isolated
bipolar, large junction areas exist between the collector
well and the substrate. As described above, junction-
isolated circuits with no special design precautions for
high temperatures can fail at temperatures as low as
200 °C.
The use of dielectric isolation (DI) or silicon-on-
insulator (SOI) eliminates the problem of junction isola-
tion in Ics by isolating each device with an oxide layer
that will (1) eliminate parasitic leakage currents between
devices and between devices and power rails, and (2)
eliminate extra junctions that form parasitic devices. The
primary benefit of SOI use for CMOS and some bipolar
ICs is the elimination of latchup. SOI eliminates the
formation of parasitic p-MOS devices in bipolar ICs and
the formation of parasitic bipolars in CMOS ICs. Figure
A-1 illustrates the reduction in large junction-isolation
areas by the use of trenches and SOI.
SOI also allows MOS devices to be fabricated in a
manner that reduces leakage currents within the MOS
device itself. The silicon film can be made thin enough to
allow the drain and source wells to contact the dielectric
layer; the junction area between the source or drain and
the channel is the width of the FET multiplied by the
thickness of the silicon film. Reducing the thickness of the
silicon film can lead to an SOI FET with leakage currents
that are orders of magnitude smaller than in a bulk FET.
Figure A-2 illustrates the leakage current as a function of
OCR for page 83
Appendix A: Silicon as a High-Temperature Material
Standard Bipolar
P+ N+ N+ P+ N+ P P+
1 1 1 1 1 1 1
",' ~ ~ " .'
Si Substrate
.
Bipolar/SIMOX
Trench N+ N+ P+ N+ P Trench
1 1 1 1 1 1 1
I ~ r I \~` 1 1
Buried Oxide
_
Si Substrate
FIGURE A-l Reduction in large junction isolation areas by the use of
trenches and SOI. SOURCE: Ibis Technology Corp. (l99l).
temperature for three types of n-MOS transistors with gate
lengths of 2 microns. Leakage currents in thin-film
transistors may not be linearly dependent on the silicon
film thickness; theoretical calculations show that the
leakage current decreases more rapidly as the thickness is
decreased. Parasitic capacitances are also reduced by
reduction of those junction areas (Swonger et al., 1991~.
While the use of SOI in bipolar devices does reduce
isolation, latchup, and parasitic MOS-device problems due
to leakage currents at high temperatures, problems such
as Vbe reduction, transistor current gain, base current
reversal, etc., still remain. These problems can be
successfully addressed through circuit and device layout
modifications.
DI techniques commercially used today include: (1)
separation by implantation of oxygen (SIMOX); (2) wafer
bonding, lapping, and etch back; and (3) V-groove
etching, polysilicon filling, and lapping of the crystalline
·. ~
silicon.
Wafer Bonding
-
Wafer bonding is the latest SOI technology. Bonded
wafer substrates can be prepared by thermally oxidizing
two wafers. The wafers are then treated so that the oxide
surfaces become hydrophilic. The oxide surfaces are then
placed face-to-face, forming a weak room-temperature
bond. Subsequent annealing at temperatures greater than
800 °C form stronger bonds so that the wafers can no
longer be separated. After bonding, one of the walers (the
83
device wafer) is thinned to the desired silicon film
thickness by grinding, electrochemical etching, and
polishing. Thin and uniform silicon layers are difficult to
produce using the wafer-bonding technique (Swonger et
al., 1991~. Wafer bonding is currently limited to silicon
film thicknesses larger than 1 Em due to thickness varia-
tions of 0.5 ,um during thinning processes. Wafer-bonding
does provide an excellent quality silicon film with very
few dislocations. The wafer-bonding process also facili-
tates the fabrication of SOI wafers with very thick buried
oxide layers. The high-quality silicon films and thick
oxides generally make wafer bonding a good technology
for high-performance bipolar applications. Dislocations
can cut through the bipolar emitter and collector, allowing
preferential diffusion and punch-through. Thicker oxide
layers reduce substrate capacitance, allowing higher-speed
bipolar performance.
Sl:MOX
In the SIMOX process, a buried SiO2 layer is formed
below the silicon wafer surface by implanting oxygen into
the wafer at sufficient dose and energy. The thickness and
quality of the silicon and SiO2 layers depend on the
oxygen dose, temperature of the wafer during implanta-
tion, and anneal temperature after the implant. Multiple
implants are used to reduce the silicon defect density. As
an example, a high-quality sample was made with a 400-
nm-thick buried oxide and a single-cr~rstal 250-nm-thick
silicon top film. The ion dose, energy, and implantation
temperature were 1.8 x 10~8 amp, 200 keV, and 620 °C,
respectively. A final post-implant anneal of 1350 °C was
used. The quality is adequate enough to fabricate 256 k
10-5
106
107
10-8
10-9
-10
-l1
- Thick SOI (40~
I 1 1 1 1 1 1 1 1 1
1.4 1.5 1.6 1.7 1.8 1.9 2.0 2.1 2.2 2.3 2.4
1 000/T(K)
FIGURE A-2 Leakage currents as function of temperature for three
types of n-MOS transistors with gate lengths of 2 microns. SOURCE:
Swonger et al. (l99l).
OCR for page 84
Materials for High-Temperature Semiconductor Devices
SRAMS. Commercial vendors offer SIMOX wafers from increased as temperature increased while the open-loop
3 in. to 200 mm diameter. SIMOX is traditionally used gain decreased with increasing temperature; this latter
for CMOS applications instead of wafer bonding because parameter is shown in Figure A-4 as a function of
thin and uniform layers can be produced (Colinge, 19931. temperature. It was reported that degradation could be
minimized by incorporating other high-temperature design
techniques into the operational amplifier design.
Lateral Isolation
In addition to vertical isolation processes afforded by
the SOI technology, a lateral isolation process is needed
to isolate devices. In SOI, thin silicon films can be etched
off between devices or consumed by local oxidation.
Lateral isolation in thick films is obtained by etching
narrow and deep trenches through the silicon layer to the
buried oxide layer. These trenches can then be filled with
an oxide.
APPLICATIONS TO DEVICE TECHNOLOGY P
Bipolar-Junction-Transistor Applications
in SOI Technology
Recently, lateral n-p-n bipolar transistors have been
fabricated using SIMOX SOI substrates. The bipolar
structures were investigated for high-frequency and smart-
power applications and no high-temperature tests were
mentioned, although the benefits of dielectric isolation
with respect to higher integration density, no latchup, less
leakage current, high-temperature operation, and noise
immunity were mentioned (Weyers et al., 1992; Parke et
al., 1993).
Operational amplifiers that used dielectrically isolated
bipolar transistors and other design techniques mentioned
above were developed in the late 1970s by Harris (Bea-
som and Patterson, 1982~. The operational amplifier was
characterized over the temperature range of 25-300 °C.
Useful circuit performance was observed up to 300 °C. In
Appendix C, Table C-1 summarizes the electrical parame-
ters of the 300 °C op amp. A similar op amp circuit
design was refabricated by Harris using a DI process flow
and bonded wafer SOI substrates (Swonger et al., 19911.
The process flows are shown in Figure A-3. Other than
dielectric isolation, no other high-temperature compensa-
tion techniques were used for this circuit design. These op
amps were also tested to 300 °C, with all devices func-
tional to that temperature. Power dissipation, input-offset
voltage, input-bias current, and input-offset current
84
CMOS Applications in SOI
A variety of CMOS circuits based on SOI has been
tested for high-temperature applications. Circuits tested
include inverters, 19 stage ring oscillators, and 4 k
through 128 k SRAMS.
Allied Signal has tested thick- and thin-film MOS-
FET-based inverter circuits to temperatures as high as
Dielectric Isolation Bonded Wafer
N
. ~__)
N+ N-
.
~ ' N+ r
b
N- |
; ~ ''' ''I'"<-" - ''"
, _ 2 .
a
~ rim ~,
_ \~ N+ J N- ~
~ 7~/~/~/~//r~///~//// / .. ,,. ~
b
N+ ) N- ~ P+ J
-Y~,,,f ,,~x,w,+, it._ _~
tf~
~,~,,,,' J .,~,,, J ~
c ~
POLY OXIDE ~
l . .
IN+=
N
N+ +
d
d
. N ~ P- l I
N+ ) ~ P+ ~, ~ 1
~ '~ ~ ~ ~ ,, _~/ in, .,
e
POLY
FIGURE A-3 Schematics of the dielectric isolation material process
flow and the bonded wafer material process flow. SOURCE: Swonger
et al. (1991).
OCR for page 85
Appends A: Silicon as a High-Temperature Material
Too
m
~ 90
>
c
._
o
c
o
80
70
60
50
Bonded Wafer
. 1 1
0 50 100
Dielectnc Isolation
150 200 250 300 350
Temperature (°C)
FIGURE A-4 Open-loop gain as a function of temperature. SOURCE:
Swonger et al. (1991).
450 °C. The leakage current is greatly reduced by the use
of SOI with two films. Inverters made in 4,000-A-thick
SOI were tested to 450 °C with fairly good results.
Leakage currents did degrade their noise margin some-
what, and threshold voltage shifts did change the output-
voltage versus input-voltage swing slightly (McKitterick,
1991).
Harris has tested 4 k SRAMs in silicon and SOI from
25-300 °C. The SOI SRAMs functioned to 300 °C, with
degradation occurring in access times and circuit standby
current. The bulk SRAMs failed at 275 °C.
SOI SRAMs (64 k) developed for military applica-
tions by Honeywell have been tested at 250 °C for 5,000
hours. The SOI CMOS process tested has not been
optimized for high-temperature operation but is being
modified to develop an SOI process capable of 300 °C
operation. Digital products to be tested include processors
and application-specific ICs as well as memories. Linear
products in development for high-temperature testing
include operational amplifiers, analog switches, voltage
references, and application-specific integrated circuits.
REFERENCES
Beasom, J.D., and R.B. Patterson. 1982. Process charac-
teristics and design methods for a 300 °C
quadoperational amplifier. IEEE Transactions on
Industrial Electronics IE-29~21: 112-117.
Colinge, J.P. 1993. SOI Technology: Materials to VLSI.
Amsterdam, Netherlands: Klewer Academic.
Estreich, D.B., and R.W. Dutton. 1982. Modeling latch-
up in CMOS integrated circuits. IEEE Transactions
on Computer-Aided Design of Integrated Circuits and
Systems CAD-14: 157-162.
Ibis Technology Corporation. 1991. SIMOX for high
temperature applications. Ibis Technology Application
Note, No. 103. Danvers, Massachusetts: Ibis Tech-
nology Corporation.
McKitterick, J.B. 1991. Very thin silicon-on-insulator
devices for CMOS at 500 °C. Pp. 37-41 in Proceed-
ings of the First International High Temperature
Electronics Conference, Albuquerque, New Mexico,
June 16-20.
Parke, S.A, C.M. Hu, and P.K. Ku. 1993. A high-
performance lateral bipolar-transistor fabricated on Si
MOX. IEEE Electron Device Letters 14~11:33-35.
Prince J.L., B.L. Draper, E.A. Rapp, J.N. Kronberg,
and L.T. Fitch. 1980. Performance of digital-inte-
grated-circuit technologies at very high temperatures.
IEEE Transactions on Components, Hybrids, and
Manufacturing Technology CHMT-3~4~:571-579.
Shoucair, F.S. 1986. Design considerations in high
temperature analog CMOS integrated-circuits. IEEE
Transactions on Components, Hybrids, and Manufac-
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Swonger, J.W., S.J. Gaul, and P.L. Heedley. 1991. An
evaluation of amp performance up to 300 °C using
dielectric isolation and bonded wafer material tech-
nologies. Pp. 281-290 in Proceedings of the First
International High Temperature Electronics Confer-
ence, Albuquerque, New Mexico, June 16-20.
Weyers, J., H. Vogt, M. Berger, W. Mach, B. Mutter-
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85
OCR for page 86
Representative terms from entire chapter:
leakage current