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Emergency and Continuous Exposure Limits for Selected Airborne Contaminants, Volume 1
INTRODUCTION
The National Research Council’s Committee on Toxicology recommends emergency exposure limits (EELs), short-term public limits (STPLs), and short-term public emergency limits (SPELs—formerly called public emergency limits, or PELs) for a variety of chemicals of concern to its sponsoring agencies. The definitions and applicability of these limits and the criteria used to establish them were originally outlined in two documents prepared by the Committee (NRC, 1964, 1971). In a revision of these documents (NRC, 1979), the Committee summarized the principles used to establish exposure limits for short durations. The Committee has also recommended continuous exposure limits (CELs) in response to specific sponsor requests.
This document is one in a series prepared by the Committee that form the basis of the recommendations for EELs and CELs for selected chemicals. Since the Committee began recommending EELs and CELs for its military sponsors (U.S. Army, Navy, and Air Force), the scope of its recommendations has been expanded in response to a request by the National Aeronautics and Space Administration. The CELs, in particular, grew out of a Navy request for exposure limits for atmospheric contaminants in submarines. The EELs and CELs have been used as design criteria by the sponsors in considering the suitability of materials for particular missions (as in a submarine or a spacecraft) and in assessing the habitability of particular enclosed environments. They are recommended for narrowly defined occupational groups and are not intended for application in general industrial settings or as exposure limits for the general public.
The EEL is defined as a ceiling limit for an unpredictable single exposure, usually lasting 60 min or less, and never more than 24 h—an occurrence expected to be rare in the lifetime of any person. It reflects an acceptance of the statistical likelihood of the occurrence of a nonincapacitating, reversible effect in an exposed population. It is designed to avoid substantial decrements in performance during emergencies and might contain no uncertainty factor. The use of uncertainty factors will depend on the specific compound in question and on the type of effect produced by the compound.
The CEL is recommended in specific situations where there may be exposure to a chemical continuously for up to 90 d. It is defined as a ceiling limit designed to avoid adverse health effects, either immediate or delayed, and to avoid degradation in crew performance that might endanger the objectives of a particular mission. Because data on continuous exposures are rarely available, uncertainty factors might be used, depending on the judgment of the Committee.
Table 1 summarizes the EELs and CELs for selected chemicals previously recommended by the Committee and revised recommendations made on the basis of information presented in this report.
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Emergency and Continuous Exposure Limits for Selected Airborne Contaminants, Volume 1
TABLE 1.
Emergency and Continuous Exposure Limits
Compound
Duration of Exposure
Recommended Exposure Limita
Previous
Current
Acetone
60 min
15,000
8,500
24 hr
2,000
1,000
90 d
300
200
Acrolein
10 min
—
0.1
60 min
0.2
0.05b
24 h
0.1
0.01b
90 d
0.1
0.01
Arsine
60 min
1.0
1.0
24 h
0.1
0.1
90 d
0.01
—
Carbon disulfide
10 min
200
200
30 min
100
100
60 min
50
50
Chloroform
60 min
200
100
24 h
30
30
90 d
3
1
Fluorine
10 min
15
15
30 min
10
10
60 min
5
7.5
Mercury vapor mg/m3
24 h
2 mg/m3
0.2
mg/m3
90 d
0.01 mg/m3
0.01
Methane
24 h
5,000
5,000
90 d
5,000
5,000
Ozone
60 min
1
1
24 h
0.1
0.1
90 d
0.02
0.02
Sulfuric acid mg/m3
10 min
5 mg/m3
5
mg/m3
30 min
2 mg/m3
2
mg/m3
60 min
1 mg/m3
1
appm, unless otherwise stated.
bTentative recommendation.
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Emergency and Continuous Exposure Limits for Selected Airborne Contaminants, Volume 1
REFERENCES
National Research Council, Ad Hoc Committee, Committee on Toxicology. 1964. Basis for Establishing Emergency Inhalation Exposure Limits Applicable to Military and Space Chemicals. Washington, D.C.: National Academy of Sciences. [5 p.]
National Research Council, Committee on Toxicology. 1971. Basis for Establishing Guides for Short-Term Exposures of the Public to Air Pollutants. Washington, D.C.: National Academy of Sciences. [15 p.]
National Research Council, Assembly of Life Sciences, Board on Toxicology and Environmental Health Hazards, Committee on Toxicology. 1979. Criteria for Short-Term Exposures to Air Pollutants. Washington, D.C.: National Academy of Sciences. [15 p.]
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Emergency and Continuous Exposure Limits for Selected Airborne Contaminants, Volume 1
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Representative terms from entire chapter:
public emergency