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APPENDIXES
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APPENDIX
A
Dispersant Products Information
TABLE A-1 Product Schedule of the Environmental Protection Agency's National
Contingency Plan, July 1987
Bulletin Dispersant Dispersant
Number Product Name Manufacturer
Previous
Acceptance
Date
BPllOOX
(hydrocarbon
solvent based)
2 Cold Clean 500
(water based)
Conco
Dispereant K
(concentrate)
4 Corexit 7664
(water based)
BP Detergents Ltd.
Pumpherston Works
Livingston, West Lothian
Scotland EH53 OLQ
Tel: 0506 31111 Telex: 72278
(John R. Nicol)
10/20/77
Essex Fire and Safety Co. 10/7/77
P.O. Box 87709
Houston, TX 77287
(713) 641-3616
(Virginia A. Watters)
Continential Chemical Co. 4/25/78
270 Clifton Bled.
Clinton, NJ 07011-3686
(202) 472-5000
(P. D. Turite)
Exxon Chemical Co.
8230 Stedman Street
Houston, TX 77029
(713) 670-1702
(Don Jacques)
309
11/1/78
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310
TABLE A-1 (Continued)
APPENDIX A
Previous
Bulletin Dispersant Dispersant Acceptance
Number Product Name Manufacturer Date
5 Corexit 8667 Exxon Chemical Co. 11/1/78
(hydrocarbon 8230 Stedman Street
solvent based) Houston, TX 77029
(713) 670-1702
(Don Jacques)
6 Corexit 9527 Exxon Chemical Co. 3/10/78
(hydrocarbon 8230 Stedman Street
solvent based) Houston, TX 77029
(713) 670-1702
(Don Jacques)
7 EC. O ATALN 'TOL ASPRA, Inc. 11/13/70
AT7 (water based) 4401 - 23rd Avenue West
Seattle, WA 98199
(206) 284-9838
(A. I. Janofsky)
Finanol OSR-7 American Petrofina, Inc. 5/21/80
(water-based P.O. Box 2159
concentrate) Dallas, TX 75221
(214) 750-2640
(Jerry W. Johnson)
Gold Crew Ara Chem, Inc. 8/31/77
Dispersant P.O. Box 5031
(water-based San Diego, CA 92105-0001
concentrate) (619) 286-4131
(Rite Jimenez McNeely)
10
Magnotox
(water-based
concentrate)
11 OFC D-609
(concentrate)
12
Magnus Maritec Int'l., Inc. 7/1/81
150 Roosevelt Place
P.O. Box 150
Palisades Park, NJ 07650
(201) 592-0700
(Andreas C. Ladjias)
Chem Link Petroleum, Inc. 8/20/79
P.O. Box 370
Sand Springs, OK 74063
(918) 245-2224
(Glenn D. Fielder)
Oil Spill
Eliminator N/T
No. 4 (hydrocarbon
solvent based)
Petrocon Marine and 5/21/80
Chemical Corp.
243-44th Street
Brooklyn, NY 11232
(212) 499-3111
(Frank B. Sidoti)
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APPENDIX A
TAT3LE A-1 (Continued)
311
Precarious
Bulletin Dispersant Dispersant Acceptance
Number Product Name Manufacturer Date
13
OSD/LT Oil Spill
Dispereant
(concentrate)
Drew Chemical Corp. 5/11/79
1 Drew Chemical Plaza
P.O. Box 157
Boonton, NJ 07005
(202) 263-7817
(Rochelle Caliber Asbell)
14 Petro-Green Petro-Green, Inc. 9/30/84
ADP-7 3952 Candlenut Lane
P.O. Box 814665
Dallas, TX 75381
(214) 484-7336
(Arnold Paddock)
15 Petromend, Petromend, Inc. 9/30/84
MP-900-W P.O. Box 47532
(water-based 8300 Sovereign Row
concentrate) Dallas, TX 75247
(214) 630-1330
(Alan Cohn)
16
17a
Proform-Pollu-
tion Control
Agent (water-
based concentrate)
Proform Products Corp. 5/9/79
220 California Avenue
Suite 100
Palo Alto, CA 94306
(415) 321-5207
(Rudolf Kruska)
18 Slik-A-Way MI-DEE Products, Inc. 10/5/78
(water-baned) 5253 Springdale Avenue
Pleasanton, CA 94566
(415) 846-8166
(Paul Spellman)
19 Dispereant 11 Dubois Chemicals 10/16/84
(concentrate) 1100 Dubois Tower
Cincinnati, OH 45202
(513) 762-6894
(W. N. Grawe)
20 Topsail No. 30
(oil and petroleum
cleaning agent)
Stutton North Corp. 1/7/85
P.O. Box 724
Mande~rille, LA 70448
(504) 626-3900
(Sic Studin)
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312
TABLE A-1 (Continued)
APPENDIX A
-
Pre~rious
Bulletin Dispereant Dispersant
Number Product Name Manufacturer
Acceptance
Date
21 Corexit 9550 Exxon Chemical Co. 5/22/85
(hydrocarbon 8230 Stedman Street
solvent based) Houston, TX 77029
(713) 670-1702
(Don Jacques)
22 Jansol~r-60
Dispersant
(principally water-
based with some
solvent)
23 Ruffnek
(oil and petroleum
cleaning agent)
Sunshine Technology Corp. 7/9/85
2475 Albany Avenue
West Hartford, CT 06117
(203 232-9227
(Stephen Kaufmann)
Matter International Corp. 7/16/85
80 First Street
Gretna, LA 70053
(504) 362-3232
(Laboratory)
24 NEOS AB 3000 NEOS Company Limited 4/22/85
"hydrocarbon 8th Floor, Kanden Building
solvent based) 2-1, Kano-cho 6-chome
Chuo-ku, Kobe 650, Japan
(078) 331-9381
(S. Miyoshi)
25 Crudex Environmental Security, Inc. 6/4/86
(organic surfactant 352 Abbey~rille Road
based) Lancaster, PA 17603
(717) 392-1251
(Jay Greene)
26 Bio Solve Metra Chem Corp. 12/22/86
(water based) 792 Hartford Pike
Shrewsbury, MA 01545
(617) 845-1193
(Mario J. Genduso)
27 NK-3 GFC Chemical Co. 2/19/87
(water based) P.O. Box 80537
Lafayette, LA 70598-0537
(318) 234-8262
(Joe Winkler)
28 Enereperee 700 BP Detergents Ltd. 7/27/87
(solvent based) Drun~horeland Road
Pumpherston Works
Li~ringeton, West Lothian
Scotland EH53 OLQ
(011-44-5016) 31111
(David Kerr)
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APPENDIX A
TABLE A-1 (Continued)
313
Previous
Bulletin Dispersant Dispersant Acceptance
Number Product Name Manufacturer Date
29 Slickgone NS DASIC International Ltd. 2/22/88
(solvent based) Winchester Hill - Romsey
Hampshire S041 7YD
England, U.K.
(0794) 512419
(John L. Belk)
30 Mare Clean 505
(solvent based)
Mitsubishi International Corp. 2/23/88
International Specialty
Chemicals Department
520 Madison Avenue
New York, NY 10022
(212) 605-2533
(K. Komatsu [FER])
aSea Master NS-555, bulletin number 17, is no longer manufactured and has been
removed from the U.S. EPA Product Schedule.
TABLE A-2 List of Dispersants Approved by the Environ-
mental Protection Service of Canada, February 1987
Product Name
Manufacturer
Corexit 9527
Corexit 9550
Corexit CRX-8
Drew Oil Dispersant LT
Enersperse 1100X
Enersperse 700
Gamelin 2000
Oilsperse 43
SlickGone LTS
Exxon/Esso Chemical
Ex~con/Esso Chemical
Ex~con/Esso Chemical
Drew Chemical
British Petroleum/
PetroCan chemicals
British Petroleum/
PetroCan Chemicals
Gamelin Chemical
Diachem Industries
Dasic International
~ .
SOURCE: Eco/Log Week, February 6,1987
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314
TABLE A-3 Composition of Some Currently Produced Oil Spill Dispersantsa
APPENDIX A
_
Base Product Composition
Hydrocarbonb BPllOOX (British
based Petroleum)
Corexit 8667
(Exxon)
Corexit 9550
Water basedC Corexit 7664
Corexit 9527
Concentrated BPllOOD
Fatty acid ester (15 wt%)
Hydrocarbon solvent (84%)
(Aromatics in solvent < 3%)
Additives (1%)
Oxyalkylated surfactant in nonaromatic
hydrocarbon solvent
Amber liquid, mild odor
Mixture of surfactant ester in mixed
oxygenated and nonaromatic hydrocarbon
solvents; contains glycol ethers
Amber liquid
Nonionic polyhydric alcohol ester of
fatty acid + 20% isopropyl alcohol
Ester surfactants in mixed oxygenated
solvents
Light-amber liquid, slight alcohol odor
Glycols
Yellow liquid, unique odor
Surfactants have infrared spectra
identical to those in BPllOOX
Amber-colored clear liquid with odor
bChemical composition terminology is that of the manufacturer.
~Water-immiscible, can be used on high-viscosity crude and residual oils,
Weathered crudes, waxy crudes, and water-in-oil emulsions.
dCan be used on light-distillate fuels and low-viscosity crude and product.
~Can be used on all types of oil.
SOURCE: Wells, 1984.
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APPENDIX A
TABLE A-4 Some Patented Oil Spill Dispersant Formulationsa
Assignee Patent Number Active Ingredients Solvent
ICI Brit. 1,338,385 Esters of tall oil fatty acid and
Non. 73 polyethylene glycol monomethyl
ether
ICI Brit. 1,338,391 Esters of tall oil fatty acid and
1973 polyethylene glycol monobenzyl
or monnonylphenyl ether
BP Brit. 1,361,179 Ethoxylated fatty alcohol Kerosene,
July 74 1.6-6.0 mol EO/mol alcohol isopropanol
Exxon U.S. appl. 457,098 Sorbitan monooleate
(April 74?) Ethoxylated sorbitan monooleate
Na dioctyl sulfosuccinate
Exxon U.S. 3,793,218 As above
(Feb. 74?)
IFP Fr. appl. Ethoxylated esters of saccharine
74/03.364 Feb.74 and oleic acid
IFP Fr. appl. Esters of ethoxylated
74/43.200 1974 trimethylolpropane monooleate
and glutamic acid
Dasic Brit. 1,404,648 Polyethylene glycol monooleate Kerosene
Intern May 75 (9%) sorbitan monooleate (3%),
monopropylene glycol (2%)
i% or ratio?]
BP Brit. 1,399,80? Polyethylene glycol esters Kerosene
July 75 of oleic acid
IFP Belg. 886,656 Polyethylene glycol monooleate
(1975?) Ethoxylated sorbitan oleate
Ethoxylated octyl phosphate
Ethoxylated tridecylphosphate
BP Brit. 1,419,803 Polyethylene glycol esters Propoxylated
Lankro Fr. 2,330,653 Monoester of polyethylene
June 77 glycol and a fatty acid
(R < 10 carbons, EO = 2)
PCUK Fr. appl. Ethoxylated/propoxylated esters
78/27.894 of an alcohol ethoxylate and
phosphoric acid
Institute Ger. Off. Diester of an ethoxylated alcohol
for Ocean- 2,626,552 and phosphoric acid
ology, Dec. 78
USSR
Institute U.S. 4,197,197 Diester of an ethoxylated alcohol
for Ocean- April 80 and phosphoric acid (R = 7 to
ology, 12 carbons, EO = 4 to 6)
USSR
PCUK Fr. 2,394,602 Mono and diesters of an alcohol
Jan. 79 ethoxylate and phosphoric acid
ICI Brit. appl. Hexamethylene diamine Hydrocarbon
79/17, 106 Ethylene/propylene oxide
May 79 condensate, nonionic surfactant
Shell Brit. 1,557,182 Mixtures of polyethylene glycol
Dec. 79 monooleate, e.g., diethylene
glycol monooleate, polyethylene
glycol monooleate
PCUK Fr. 2,439,817 Ethoxylated/propoxylateld esters
(1980?) of an ethoxylated/propoxylated
alcohol and phosphoric acid
Labofina Fr. 2,479,251 Tall oil estere (35~), ethyldioxitol
(1980?) (47~), sorbitan monolaurate (7~)
water (1096), calcium sulfonate (1%)
315
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316
TABLE A-4 (Continued)
APPENDIX A
Assignee Patent Number Acti~re Ingredients Sol~rent
Coeden U.S. 469,603 Sorbitan monooleate
Tech. Sept. 84 Ethoxylated sorbitan monooleate
tFinasol) Sodium diethylhexyl sulfosuccinate
Ex~con U.S. 4,502,962 Sorbitan monooleate Hydrocarbon
March 85 Ethoxylated sorbitan monooleate
(1976?) Ethoxylated sorbitan trioleate
Sodium ditridecyl sulfosuccinate
of fatty acide and aryl, Butanol
alky., alkyl-ether, or alkyl- (m.w. 90-250)
aryl sulfate/sulfonate; e.g.,
Na lauryl sulfate, alkyl
bensene sulfonates
KEY: ICI--Imperial Chemical Industries, United Kingdom; BP--British Petroleum, United
Kingdom; IFP--Institute Francaise du Petrole, France; and PCUK--Produits Chemique Ugine
Kuhlman, France.
aChemical composition terminology is that of the manufacturer.
SOURCES: Wells, 1984; Cane~rari, private communication.
Representative terms from entire chapter:
dispersant dispersant dispersant