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OCR for page 58
Carbon Filtration for Reducing Emissions from Chemical Agent Incineration
Appendix B
Consolidated Exhaust Gas Characteristics for the JACADS and TOCDF Baseline Incineration Systems
Emissions test results were originally reported in the units required by the cognizant agencies at the time. Over time, the reporting units have changed and are now different for each facility. Consequently, direct comparisons and meaningful summaries require converting results into common units. The information in this appendix is standardized to Environmental Protection Agency (EPA) reference conditions (68°F for temperature; 760 mm Hg for pressure; 0 percent for moisture; and 7 percent for residual oxygen content) and conventional EPA regulatory units (ppmdv for gaseous criteria pollutants and acid gases; mg/dsm 3 for particulates; μg/dsm3 for individual elements; and ng/dsm3 at 7 percent O2 for trace organics). In developing this appendix, the committee reviewed the underlying laboratory and field reports to verify the overall accuracy of data reduction and quality assurance warnings. Reported results were compared to database values prior to standardization to eliminate transcription errors and identify errors in data reduction.
OCR for page 59
Carbon Filtration for Reducing Emissions from Chemical Agent Incineration
TABLE B-1 Exhaust Gas Characteristics for the JACADS and TOCDF Baseline Incineration Systems
Risk-Specific Dose or Reference Air Concentration (RsD or RAC)a
Total Runs
Nondetects Lower than Lowest Detected Valuesb
Detected Values Only
Detected Values
Average or DL ppbdv
Values are at 7% O2 Unless Otherwise Specified
μg/m3
N
N
Detection Limit
N
Minimum
Average
Maximum
Exhaust Gas Characteristics
Temperature (ºF)
155
155
180
208.23
280
100%
Flow rate (dsft3/min)
149
149
2,275
6,043
11,493
100%
Oxygen (%)
162
162
1.2
12.955
15.1
100%
Moisture (%)
158
158
31.3
40.543
56.2
100%
Combustion Quality Indicators (ppmdv)
Carbon monoxide
35
0
35
2
39
62
100%
Total hydrocarbons as carbon
20
0
20
2.6
6.6
9.0
100%
Chemical Agents (ng/dsm3)
GB (Sarin)
28
28
3.6
0
0%
0.0006
HD (mustard gas)
12
12
230
0
0%
0.035
VX
0
0
0
Particulates
PM (gr/dsm3)
103
0
103
0.9
14.7
50
100%
PM (gr/dscf)
103
103
103
0.0004
0.006
0.022
100%
CAA Acid Gas HAPs (ppmdv)
Hydrogen chloride
60
44
16
0.01
11
44.16
27%
11,172
Chlorine gas
6
3
(0.03)
0
0%
(30.00)
CAA Trace Element HAPs (μg/dsm3)
Arsenic
(2.3)
49
37
(0.02)
12
1
10
42
24%
Beryllium
(4.2)
35
0
2
0.008
0.008
0.008
6%
Cadmium
(5.6)
35
7
(0.20)
28
0
6
50
80%
Cobalt
9
0
9
0.08
0.23
0.8
100%
Chromium (total)
1,000,000
46
0
41
0.22
7.4
56
89%
Chromium (hexavalent)
(0.83)
20
13
(0.3)
7
0.34
1.8
4.2
35%
Mercury
300
43
0
26
0.25
7.1
25
60%
0.9
OCR for page 60
Carbon Filtration for Reducing Emissions from Chemical Agent Incineration
Risk-Specific Dose or Reference Air Concentration (RsD or RAC)a
Total Runs
Nondetects Lower than Lowest Detected Valuesb
Detected Values Only
Detected Values
Average or DL ppbdv
Values are at 7% O2 Unless Otherwise Specified
μg/m3
N
N
Detection
Limit
N
Minimum
Average
Maximum
CAA Trace Element HAPs (μg/dsm3)
Manganese
30
0
30
0.43
233
2,105
100%
Phosphorus
12
0
12
84
1,508
5,934
100%
Antimony
300
35
28
(0.11)
7
0.16
1.9
5.4
20%
Selenium
24
0
6
0.16
6.2
15
25 %
Other Trace Elements (μg/dsm3)
Aluminum
9
0
9
82
98
125
100%
Barium
50,000
42
0
34
1
14
86
81%
Boron
12
0
12
0.41
36
257
100%
Copper
24
0
19
0.20
49
294
79%
Potassium
20
0
14
19
1,253
5,940
70%
Nickel
(42)
19
0
17
0.16
33
216
89%
Lead
90
49
0
34
0.16
122
1,704
69%
Tin
24
0
(14)
18
2.0
122
692
75%
Thallium
35
35
(0.1)
0
0%
Vanadium
9
9
(0.81)
0
0%
Zinc
39
0
35
7.5
119
488
90%
CAA Trace Organic HAPs (ng/dsm3)
4-aminobiphenyl
12
12
(6,074)
0
0%
(0.9)
Aniline
(14,000)
12
12
(6,074)
0
0%
(2)
Benzene
(12,000)
39
0
23
0.10
17,401
99,286
59%
5
Benzidene
(0.15)
12
12
(9,994)
0
0%
(1)
Bromoform
39
0
26
0.0002
6,234
18,230
67%
1
Bromomethane
800
21
14
(2,904)
7
3,690
5,320
6,775
33%
1
Butadiene
18
18
(11,564)
0
0%
(5)
OCR for page 61
Carbon Filtration for Reducing Emissions from Chemical Agent Incineration
Risk-Specific Dose or Reference Air Concentration (RsD or RAC)a
Total Runs
Nondetects Lower than Lowest Detected Valuesb
Detected Values Only
Detected Values
Average or DL ppbdv
Values are at 7% O2 Unless Otherwise Specified
μg/m3
N
N
Detection Limit
N
Minimum
Average
Maximum
CAA Trace Organic HAPs (ng/dsm3)
Carbon tetrachloride
(670)
26
18
(2,219)
8
2,823
26,655
86,623
31%
4
Chloroform
(430)
33
0
21
0.0001
8,069
42,304
64%
2
Carbon disulfide
200,000
29
23
(812)
6
14,020
25,127
47,170
21%
8
Dibenzofuran
12
12
(6,074)
0
0%
(0.9)
1,3-dichlorobenzene
10,000
12
12
(6,074)
0
0%
(1)
1,4-dichlorobenzene
10,000
12
12
(6,074)
0
0%
(1)
3,3-dichlorobenzidine
12
12
(10,974)
0
0%
(1)
Trans-1,3-dichloropropene
(0.029)
15
15
(2,219)
0
0%
(0.5)
3,3-dimethylbenzidene
12
12
(6,074)
0
0%
(0.7)
2,4-dinitrotoluene
(110)
12
12
(6,074)
0
0%
(0.8)
Ethlylene dibromide
(0.45)
12
12
(2,336)
0
0%
(0.3)
Ethylbenzene
26
19
(403)
7
521
2,016
4,250
27%
0.5
Ethyl chloride
18
18
(1,958)
0
0%
(0.7)
Bis(2-ethylhexyl)phthalate
(42,000)
15
10
(6,178)
5
10,723
94,214
272,641
33%
6
N-hexane
21
17
(1,958)
4
2,336
2,523
2,682
19%
0.7
Hexachlorobenzene (total)
12
12
(6,074)
0
0%
(0.5)
Hexachlorobutadiene
12
12
(6,074)
0
0%
(0.5)
Hexachlorocyclopentadiene
5,000
12
12
(6,074)
0
0%
(0.5)
Hexachloroethane
12
12
(6,074)
0
0%
(0.6)
Isophorone
12
12
(6,074)
0
0%
(1)
Methyl ethyl ketone
80,000
24
20
(10,572)
4
69,856
78,682
92,667
17%
26
Methylene chloride
(2,400)
39
15
(0.00006)
18
0.0004
205,026
3,088,889
55%
58
2-methylphenol [o-cresol]
50,000
15
12
(6,074)
3
77,222
164,605
264,762
20%
37
Naphthalene
12
12
(6,074)
0
0%
(1)
Nitrobenzene
800
12
12
(6,074)
0
0%
(1)
4-nitrophenol
12
12
(7,722)
0
0%
(1)
Styrene
35
19
(1,283)
16
3,947
42,283
514,734
46%
17
1,1,2,2-tetrachloroethane
(170)
27
25
(1,283)
2
2,206
2,206
2,206
7%
0.3
1,1,2-trichloroethane
(630)
18
18
(1,958)
0
0%
(0.4)
Tetrachloroethylene
(21,000)
6
3
(3,349)
3
4,277
16,135
26,476
50%
2
Toluene
300,000
36
0
24
0.00
5,960
28,234
67%
0.8
Vinyl bromide
9
9
(9,789)
0
0%
(2)
Vinylidene chloride
3
3
(2,219)
0
0%
(0.6)
OCR for page 62
Carbon Filtration for Reducing Emissions from Chemical Agent Incineration
Risk-Specific Dose or Reference Air Concentration (RsD or RAC)a
Total Runs
Nondetects Lower than Lowest Detected Valuesb
Detected Values Only
Detected Values
Average or DL ppbdv
Values are at 7% O2 Unless Otherwise Specified
μtg/m3
N
N
Detection Limit
N
Minimum
Average
Maximum
Caa Trace Organic HAPs (ng/dsm3)
Methyl chloride
12
9
(3,527)
3
29,938
1,135,218
3,088,889
25%
541
Vinyl chloride
(1,400)
26
18
(415)
8
996
5,325
21,502
31%
2
Vinyl acetate
24
22
(1,324)
2
1,497
1,497
1,497
8%
0.4
Xylene(m & p)
80,000
22
17
(434)
5
456
2,910
5,169
23%
0.7
Xylene(o)
80,000
22
0
6
934
2,066
3,676
27%
0.5
Pentachlorophenol (total)
30,000
12
12
(30,370)
0
0%
(3)
Phenol
30,000
12
7
(6,765)
5
7,125
9,632
13,440
42%
2
1,4-benzenediamine
12
12
(6,074)
0
0%
(1)
1,2,4-trichlorobenzene
20,000
12
12
(6,074)
0
0%
(0.8)
4-methylphenol [p-cresol]
50,000
3
1
(6,178)
2
51,323
943,503
1,835,683
67%
210
3-methylphenol [m-cresol]
50,000
3
0
2
2,780
12,422
22,063
67%
3
Dimethylphthalate
9
0
8
9,953
30,987
99,942
89%
4
Di-n-butylphthalate
100,000
3
0
3
10,811
31,013
66,190
100%
3
Cis-1,3-dichloropropene
(0.029)
3
3
(2,336)
0
0%
(0.5)
Other Trace Organics (ng/dsm3)
Acenaphthene
12
12
(6,074)
0
0%
(0.9)
Acenaphthylene
12
0
1
1,000
1,000
1,000
8%
0.05
Acetone
39
28
0.001
32,851
110,317
72%
14
Acetophenone
100,000
12
11
(6,074)
1
6,828
6,828
6,828
8%
1
2-acetylaminofluorene
12
12
(60,739)
0
0%
(7)
3-amino-9-ethycarbazole
12
12
(60,739)
0
0%
(7)
Anthracene
12
12
(6,074)
0
0%
(0.8)
Aramite
12
12
(6,074)
0
0%
(0.4)
Benzoic acid
12
12
(60,739)
0
0%
(12)
Benz(a)anthracene
(11)
12
12
(6,074)
0
0%
(0.6)
Bromodichloromethane
21
12
(2,937)
9
3,271
6,968
13,440
43%
1
Benzo(b)fluoranthene
12
12
(6,074)
0
0%
(0.6)
Benzo(j)fluoranthene
12
12
(6,074)
0
0%
(0.6)
Benzo(k)fluoranthene
12
12
(6,074)
0
0%
(0.6)
Benzo(g,h,i)perylene
12
12
(6,074)
0
0%
(0.5)
Benzo(a)pyrene
(3)
12
12
(6,074)
0
0%
(0.6)
Bromodichloromethane
12
12
(6,074)
0
0%
(0.7)
OCR for page 63
Carbon Filtration for Reducing Emissions from Chemical Agent Incineration
Risk-Specific Dose or Reference Air Concentration (RsD or RAC)a
Total Runs
Nondetects Lower than Lowest Detected Valuesb
Detected Values Only
Detected Values
Average or DL ppbdv
Values are at 7% O2 Unless Otherwise Specified
μtg/m3
N
N
Detection Limit
N
Minimum
Average
Maximum
Other Trace Organics (ng/dsm3)
Benzyl alcohol
12
12
(6,074)
0
0%
(1)
Benzaldehyde
12
10
(6,074)
2
9,438
19,791
30,145
17%
4
Benzenethiol
12
12
(60,739)
0
0%
(13)
Biphenyl
12
12
(6,074)
0
0%
(0.9)
Bromophenyl-phenylether(4)
12
12
(6,074)
0
0%
(0.5)
Butylbenzylphthalate
12
12
(6,074)
0
0%
(0.5)
Cis-1,4-dichloro-2-butene
21
21
(1,958)
0
0%
(0.4)
Trans-1,4-dichloro-2-butene
12
12
(2,336)
0
0%
(0.4)
Cis-1,3-dichloropropene
(2.2)
31
18
(403)
13
478
140,561
898,154
42%
30
4-chloroaniline
9
9
(6,074)
0
0%
(1)
Bis(2-chloroethoxy)methane
12
12
(6,074)
0
0%
(2)
Bis(2-chloroethyl)ether
(0.16)
12
12
(6,074)
0
0%
(1)
2,2-oxybis(1-chloropropane)
12
12
(6,074)
0
0%
(2)
Chlorobenzilate
12
12
(6,074)
0
0%
(0.4)
4-chloro-3-methylphenol
12
12
(6,074)
0
0%
(1)
1-chloronaphthalene
12
12
(6,074)
0
0%
(0.9)
2-chloronaphthalene
12
12
(6,074)
0
0%
(0.9)
2-chlorophenol
12
12
(6,074)
0
0%
(1)
4-chlorophenyl-phenylether
12
12
(6,074)
0
0%
(0.7)
Chrysene
12
12
(6,074)
0
0%
(0.6)
2-chloropropane
12
12
(2,336)
0
0%
(0.7)
Chlorobenzenes (total)
29
22
(434)
7
539
2,519
3,942
24%
(0.09)
4,4-DDE
12
12
(60,739)
0
0%
(5)
Diallate
12
12
(11,681)
0
0%
(1)
Dibenz(a,h)anthracene
(0.71)
12
12
(6,074)
0
0%
(0.52)
Dibromochloropropane
12
12
(60,739)
0
0%
(6)
di-n-butyl phthalate
100,000
12
12
(6,074)
0
0%
(0.5)
1,2-dichlorobenzene
10,000
12
12
(6,074)
0
0%
(1)
2,4-dichlorophenol
3,000
12
12
(6,074)
0
0%
(0.9)
2,6-dichlorophenol
12
12
(6,074)
0
0%
(0.9)
Dichloromethane
9
3
(1,958)
6
7,201
9,353
11,797
67%
3
Dibromomethane
18
18
(2,219)
0
0%
(0.3)
OCR for page 64
Carbon Filtration for Reducing Emissions from Chemical Agent Incineration
Risk-Specific Dose or Reference Air Concentration (RsD or RAC)a
Total Runs
Nondetects Lower than Lowest Detected Valuesb
Detected Values Only
Detected Values
Average or DL ppbdv
Values are at 7% O2 Unless Otherwise Specified
μg/m3
N
N
Detection Limit
N
Minimum
Average
Maximum
Other Trace Organics (ng/dsm3)
1,1-dichloroethene
25
25
(415)
0
0%
(0.1)
1,2-dichloroethene
12
12
(1,958)
0
0%
(0.5)
1,2-dichloropropane
27
25
(1,103)
2
1,047,846
1,047,846
1,047,846
7%
223
1,1-dichloroethane
(380)
18
18
(1,958)
0
0%
(0.5)
1,2-dichloroethane
(200)
15
15
(2,219)
0
0%
(0.5)
Dihydrosafrole
12
12
(7,722)
0
0%
(1)
Diethylphthalate
800,000
15
12
(6,074)
3
66,190
400,164
933,286
20%
43
P-dimethylaminoazobenzene
12
12
(6,074)
0
0%
(0.6)
7,12-dimethylbenzo(a)anthracene
12
12
(6,074)
0
0%
(0.6)
a,a-dimethylphenethyl-amine
12
12
(6,074)
0
0%
(1)
2,4-dimethylphenol
12
12
(6,074)
0
0%
(1)
Dimethylphthalate
12
11
(5,840)
1
41,456
41,456
41,456
8%
5
1,3-dinitrobenzene (m,o,p)
12
12
(6,074)
0
0%
(0.9)
4,6-dinitro-2-methylphenol
12
12
(6,074)
0
0%
(1)
2,4-dinitrophenol
12
12
(30,370)
0
0%
(4)
2,6-dinitrotoluene
12
9
(6,074)
3
25%
(0.8)
Dioxathion
12
12
(60,739)
0
0%
(3)
Di-n-octylphthalate
15
14
(5,988)
1
48,540
48,540
48,540
7%
4
1,2-diphenylhydrazine
(4.5)
12
12
(6,074)
0
0%
(0.6)
Diphenylamine
12
12
(6,074)
0
0%
(0.9)
Ethylmethanosulfonate
12
12
(6,074)
0
0%
(1)
Ethylparathion
12
12
(60,739)
0
0%
(12)
Fluoranthene
12
12
(6,074)
0
0%
(0.7)
Fluorene
12
12
(6,074)
0
0%
(0.7)
Freon 12
12
12
(2,336)
0
0%
(0.5)
Freon 113
18
18
(1,958)
0
0%
(0.3)
2-hexanone
27
25
(600)
2
3,500
3,500
3,500
7%
0.8
Heptachlor
(7.7)
12
12
(44,800)
0
0%
(3)
Hexachlorophene
300
12
12
(6,074)
0
0%
(0.4)
Hexachloropropene
12
12
(7,095)
0
0%
(0.7)
Indeno(1,2,3-cd)pyrene
12
12
(6,074)
0
0%
(0.5)
Isosafrole
12
12
(6,074)
0
0%
(0.9)
Methapyrilene
12
12
(6,074)
0
0%
(0.6)
OCR for page 65
Carbon Filtration for Reducing Emissions from Chemical Agent Incineration
Risk-Specific Dose or Reference Air Concentration (RsD or RAC)a
Total Runs
Nondetects Lower than Lowest Detected Valuesb
Detected Values Only
Detected Values
Average or DL ppbdv
Values are at 7% O2 Unless Otherwise Specified
μg/m3
N
N
Detection Limit
N
Minimum
Average
Maximum
Other Trace Organics (ng/dsm3)
4-methyl-2-pentanone
24
23
(1,283)
1
10,370
10,370
10,370
4%
2
Methoxyclor
50,000
12
12
(60,739)
0
0%
(4)
3-methylcholanthrene
(3.7)
12
12
(6,074)
0
0%
(0.5)
Methylmethanesulfonate
12
12
(6,074)
0
0%
(1)
3,4-methylphenanthrene
12
12
(6,074)
0
0%
(0.8)
2-methylnaphthalene
12
12
(6,074)
0
0%
(1)
2-methyl-5-nitroaniline
12
12
(60,739)
0
0%
(11)
1-naphthylamine
12
12
(6,074)
0
0%
(1)
2-naphthylamine
12
12
(6,074)
0
0%
( 1 )
2-nitrophenol
12
12
(6,074)
0
0%
(1)
4-nitroquinoline-1-oxide
12
12
(6,074)
0
0%
(0.6)
N-nitrozo-di-n-butylamine ng/dsm3
12
12
(6,074)
0
0%
(1)
N-nitroso-di-n-propylamine
12
12
(6,074)
0
0%
(1)
N-nitrosodiethylamine
(0.23)
12
12
(6,074)
0
0%
(1)
N-nitrosodimethylamine
12
12
(6,074)
0
0%
(2)
N-nitrophenylamine
12
12
(6,074)
0
0%
(1)
1,4-naphthoquinone
12
12
(6,074)
0
0%
(1)
5-nitroacenaphthene
12
12
(60,739)
0
0%
(7)
2-nitroaniline
12
12
(35,474)
0
0%
(6)
3-nitroaniline
12
12
(35,474)
0
0%
(6)
4-nitroaniline
12
12
(35,474)
0
0%
(6)
2-propanol
12
12
(230,226)
0
0%
(92)
1,1,1,2-tetrachloroethane
12
12
(2,336)
0
0%
(0.5)
Trans-1,2-dichloroethane
(38)
15
15
(1,958)
0
0%
(0.5)
Trichloroethane
3
3
(2,219)
0
0%
(0.4)
1,1,1-trichloroethane
31
26
(403)
5
479
9,131
20,416
16%
2
Tetrachloroethene
31
22
(403)
9
428
2,814
8,541
29%
0.4
Trichlorofluoromethane
300,000
18
18
(1,958)
0
0%
(0.3)
1,1,2-trichloroethene
7
6
(0)
1
0.0003
0.0003
0.0003
14%
0.00000005
Trichloroethylene
(7,700)
15
15
(1,958)
0
0%
(0.4)
1,2,3-chloropropane
3
3
(3,349)
0
0%
(1)
Trans-1,3-dichloropropene
(0.029)
15
15
(2,219)
0
0%
(0.5)
OCR for page 66
Carbon Filtration for Reducing Emissions from Chemical Agent Incineration
Risk-Specific Dose or Reference Air Concentration (RsD or RAC)a
Total Runs
Nondetects Lower than Lowest Detected Valuesb
Detected Values Only
Detected Values
Average or DL ppbdv
Values are at 7% O2 Unless Otherwise Specified
μg/m3
N
N
Detection Limit
N
Minimum
Average
Maximum
Other Trace Organics (ng/dsm3)
Bromoethane
9
9
(11,564)
0
0%
(3)
N-nitrosomethylethylamine
12
12
(6,074)
0
0%
(2)
N-nitrosomorpholine
12
12
(6,074)
0
0%
(1)
N-nitrosopiperidine
12
12
(6,074)
0
0%
(1)
N-nitrosopyrrolidine
(16)
12
12
(6,074)
0
0%
(2)
5-nitro-o-toluidine
12
12
(6,074)
0
0%
(1)
Pentachlorobenzene (total)
800
12
12
(7,095)
0
0%
(0.7)
Penthachloroethane
12
12
(6,074)
0
0%
(0.7)
Pentachloronitrobenzene
(140)
12
12
(30,370)
0
0%
(3)
Phenacetin
12
12
(6,074)
0
0%
(0.8)
Phenanthrene
12
11
(6,074)
1
8,752
8,752
8,752
8%
1
2-picoline
12
12
(6,074)
0
0%
(2)
Pronamide
(2,200)
12
12
(6,074)
0
0%
(0.6)
Pyrene ·
12
12
(6,074)
0
0%
(0.7)
Pyridine
1,000
12
12
(11,681)
0
0%
(4)
Quinoline
12
12
(60,739)
0
0%
(11)
Safrole
12
12
(6,074)
0
0%
(0.9)
1,2,4,5-tetrachlorobenzene
300
12
12
(6,074)
0
0%
(0.7)
2,3,4,6-tetrachlorophenol
30,000
12
12
(30,370)
0
0%
(3)
P-toludine
12
12
(60,739)
0
0%
(14)
2-toluidine
12
12
(6,074)
0
0%
(1)
Tributylamine
12
12
(60,739)
0
0%
(8)
2,4,5-trichlorophenol
100,000
12
12
(6,074)
0
0%
(0.7)
2,4,6-trichlorophenol
(1,800)
12
12
(6,074)
0
0%
(0.7)
0,0,0-triethylphosphorothioate
12
12
(60,739)
0
0%
(10)
1,3,5-trinitrobenzene
12
12
(6,074)
0
0%
(0.7)
Chloromethane
28,000
12
9
(3,349)
3
705,692
786,818
904,603
25%
375
Total xylene
80,000
3
2
(1,283)
1
1,986
1,986
1,986
33%
0.4
Trans-l,2-dichloroethylene
3
3
(2,336)
0
0%
(0.6)
N,n'-diisopropylcarbodiimide
6
6
(52,000)
0
0%
(10)
Diisopropylmethylphosphonate
6
6
(60,739)
0
0%
(10)
1,2,3-trichlorophenol
6
6
(2,000)
0
0%
(0.2)
OCR for page 67
Carbon Filtration for Reducing Emissions from Chemical Agent Incineration
Risk-Specific Dose or Reference Air Concentration (RsD or RAC)a
Total Runs
Nondetects Lower than Lowest Detected Valuesb
Detected Values Only
Detected Values
Average or DL ppbdv
Values are at 7% O2 Unless Otherwise Specified
μg/m3
N
N
Detection Limit
N
Minimum
Average
Maximum
Polychlorinated Dibenzo-P-Dioxins and Dibenzo Furans (ng/dsm3)
2,3,7,8-tetrachlorodibenzo-p-dioxin
(0.00022)
32
31
(0.0002)
1
0.002
0.002
0.002
3%
0.0000002
Tetrachlorodibenzo-p-dioxins (total)
47
13
(0.0004)
36
0.001
0.110
0.968
72%
0.000008
2,3,7,8-tetrachlorodibenzofuran
32
9
(0.002)
26
0.003
0.015
0.066
74%
0.000001
Tetrachlorodibenzofurans (total)
50
0
51
0.004
0.208
1.244
96%
0.00002
1,2,3,7,8-pentachlorodibenzo-p-dioxin
32
32
(0.001)
0
0%
(0.0000001)
Pentachlorodibenzo-p-dioxins (total)
43
28
(0.001)
15
0.005
0.181
0.877
33%
0.00001
1,2,3,7,8-pentachlorodibenzofuran
32
30
(0.001)
2
0.054
0.064
0.074
6%
0.000005
2,3,4,7,8-pentachlorodibenzofuran
32
29
(0.0005)
3
0.041
0.086
0.159
9%
0.000006
Pentachlorodibenzofurans (total)
47
17
(0.001)
30
0.004
0.357
1.815
60%
0.00003
1,2,3,4,7,8-hexachlorodibenzo-p
dioxin
(0.0077)
32
32
(0.0002)
0
0%
(0.00000001)
1,2,3,6,7,8-hexachlorodibenzo
p-dioxin
(0.0077)
32
32
(0.0001)
0
0%
(0.00000001)
1,2,3,7,8,9-hexachlorodibenzo-p
dioxin
(0.0077)
32
31
(0.0002)
6
0
0.0211
0.1269
17%
0.000001
Hexachlorodibenzo-p-dioxins (total)
47
28
(0.0002)
19
0.006
0.528
2.860
38%
0.00003
1,2,3,4,7,8-hexachlorodibenzofuran
32
27
(0.0002)
5
0.12
0.20
0.31
14%
0.00001
1,2,3,6,7,8-hexachlorodibenzofuran
32
28
(0.0001)
9
0
0.0283
0.0861
26%
0.000002
1,2,3,7,8,9-hexachlorodibenzofuran
32
32
(0.0002)
0
0%
(0.00000001)
2,3,4,6,7,8-hexachlorodibenzofuran
32
27
(0.0002)
10
0
0.0212
0.1776
29%
0.000001
Hexachlorodibenzofurans (total)
47
20
(0.0003)
27
0.0059
0.3394
1.1381
54%
0.00002
1,2,3,4,6,7,8-heptachlorodibenzo-p
dioxin
32
23
(0.0004)
9
0.0051
0.0777
0.2982
26%
0.000004
Heptachlorodibenzo-p-dioxins (total)
47
28
(0.0004)
19
0.005
0.281
1.047
38%
0.00002
1,2,3,4,6,7,8-heptachlorodibenzofuran
32
25
(0.0003)
7
0.0051
0.0887
0.1822
20%
0.000005
1,2,3,4,7,8,9-heptachlorodibenzofuran
32
28
(0.0001)
9
0
0.0576
0.2157
26%
0.000003
Heptachlorodibenzofurans (total)
44
17
(0.0003)
27
0.007
0.204
1.138
57%
0.00001
Octachlorodibenzo-p-dioxin
47
27
(0.002)
20
0.015
0.183
0.634
40%
0.00001
Octachlorodibenzofuran
50
42
(0.001)
8
0.018
0.152
0.426
15%
0.000008
Total dioxins & furans
40
0
40
0.010
1.372
8.645
100%
0.00009
International toxic equivalency ( 1989
36
36
39
0.001
0.037
0.206
100%
0.000003
ITEQ calculated setting all BDL values to 0
35
0
35
0.0
0.010
0.131
100%
0.000001
a Average annual reference air concentrations (RAC) and risk specific dose (RsD) values in μg/m3 are taken from 40 CFR 266, Appendices IV and V. RsD values are shown in parentheses. The RAC is 0.1 μg/m3 for SOPCs without a pollutant-specific RAC or RsD. Since the emitted concentration ranges are between 642,000 (MPF), 919,000 (LIC), and 1,350,000 (DFS) times greater than the annual average concentration represented by the RAC and RsD, to compare these inhalation pathway-based concentrations with measured concentrations and detection limits, multiply the RAC or RsD by 1,000,000 for particulates and metals. The multiplier for trace organic emissions is 1,000,000,000 to account for the difference in reported units.
b Nondetected concentrations with detection limits above detected values for other sampling intervals have been excluded from the table to facilitate summary presentation of the data. To determine the number of these runs, subtract the number of detects and nondetects less than the lowest detected value from the total number of runs.
OCR for page 68
Carbon Filtration for Reducing Emissions from Chemical Agent Incineration
Source: Compiled from data in sources listed below.
JACADS Data Sources:
Metco Environmental. 1992a. Source Emissions Survey of Johnston Atoll Chemical Agent Disposal System Liquid Incinerator Stack [LIC/GB]. Prepared for Southern Research Institute, August 1992. Addison, Texas: Metco Environmental.
Metco Environmental. 1992b. Source Emissions Survey of Johnston Atoll Chemical Agent Disposal System Liquid Incinerator Stack [LIC/VX], February and March 1992. Prepared for Southern Research Institute, February 1992. Addison, Texas: Metco Environmental.
Raytheon Engineers & Constructors, Inc. 1995. RCRA Trial Burn Report for Agent GB/Dunnage, in the Dunnage Incinerator at the Johnston Atoll Chemical Agent Disposal System [DUN/GB]. Prepared for Program Manager for Chemical Demilitarization, March 1995. Philadelphia, Pa.: Raytheon Engineers & Constructors, Inc.
SRI. 1991. Results of the RCRA Trial Burn with GB Feed for the Liquid Incinerator at the Johnston Atoll Chemical Agent Disposal System [LIC/GB]. Prepared for Program Manager for Chemical Demilitarization, June 17, 1991. Birmingham, Ala.: Southern Research Institute.
SRI (Southern Research Institute). 1992a. Results of the RCRA Trial Burn with VX Feed for the Liquid Incinerator at the Johnston Atoll Chemical Agent Disposal System, Volume IV (SRI-APC-92-384-7530.11.1-I) [LIC/VX]. Prepared for Program Manager for Chemical Demilitarization. Birmingham, Ala.: Southern Research Institute.
SRI. 1992b. Results of the RCRA Trial Burn of the Metal Parts Furnace System with HD at the Johnston Atoll Chemical Agent Disposal System, Volume II (SRI-APC-92-834-7530.9.l-I) [MPF/HD]. Prepared for Program Manager for Chemical Demilitarization. Birmingham, Ala.: Southern Research Institute.
SRI. 1992c. Results of the RCRA Demonstration Burn with HD Feed for the Liquid Incinerator at the Johnson Atoll Chemical Agent Disposal System, Volume IV, Appendix F (SRI-APC-92-7530.10.1-I) [LIC/HD]. Prepared for Program Manager for Chemical Demilitarization. Birmingham, Ala.: Southern Research Institute.
United Engineers (United Engineers & Constructors, Inc.). 1992. RCRA Trial Burn Report for HD-Mustard Ton Containers-Metal Parts Furnace at the Johnston Atoll Chemical Agent Disposal System [MPF/HD]. Prepared for Program Manager for Chemical Demilitarization, December 16, 1992. Philadelphia, Pa.: United Engineers & Constructors, Inc.
United Engineers. 1993. Results of the Demonstration Test Burn for Thermal Destruction of Agent HD in the Johnston Atoll Chemical Agent Disposal System Liquid Incinerator, [LIC/HD]. Prepared for Program Manager for Chemical Demilitarization, February 1993. Philadelphia, Pa.: United Engineers & Constructors, Inc.
TOCDF Data Sources:
Alliance Technologies Corporation. 1992. RCRA Compliance Test Results with Mixed Agent HD/Munitions for the Cryofracture Program on the Deactivation Furnace System, Chemical Agent Munitions Disposal System [DSF/HD]. Prepared for Program Manager for Chemical Demilitarization. Windsor, Conn.: TRC Environmental Corp.
EG&G. 1995. Tooele Chemical Disposal Facility (TOCDF), Surrogate Trial Burn Report for Liquid Incinerator Number 1 [LIC/STB]. Prepared for Program Manager for Chemical Demilitarization, November 29, 1995. Tooele, Utah: EG&G Defense Materials, Inc.
EG&G. 1997a. MPF GB ATB Report, Rev. 2 (partial report), [MPF/GB]. Prepared for Southern Research Institute, December 31, 1997a. Tooele, Utah: EG&G Defense Materials, Inc.
OCR for page 69
Carbon Filtration for Reducing Emissions from Chemical Agent Incineration
EG&G. 1997b. Tooele Chemical Agent Disposal Facility (TOCDF), RCRA Agent Trial Burn Report for the Liquid Incinerator System #2 [LIC/GB]. Prepared for Southern Research Institute, October 27, 1997. Tooele, Utah: EG&G Defense Materials, Inc.
EG&G. 1997c. Tooele Chemical Agent Disposal Facility (TOCDF), RCRA Agent Trial Burn Report for the Metal Parts Furnace, Appendices A-K [MPF/GB]. Prepared for Program Manager for Chemical Demilitarization, August 15, 1997. Tooele, Utah: EG&G Defense Materials, Inc.
EG&G. 1997d. Tooele Chemical Agent Disposal Facility (TOCDF), RCRA Agent Trial Burn Report for the Liquid Incinerator System #1, Appendices A-K, [LIC/GB]. Prepared for Program Manager for Chemical Demilitarization, July 7, 1997. Tooele, Utah: EG&G Defense Materials, Inc.
EG&G. 1997e. Tooele Chemical Agent Disposal Facility (TOCDF), DFS TSCA Demonstration Test Burn Report for the Deactivation Furnace System [DFS/GB]. Prepared for Program Manager for Chemical Demilitarization, April 24, 1997. Tooele, Utah: EG&G Defense Materials, Inc.
EG&G. 1997f. Tooele Chemical Agent Disposal Facility (TOCDF), RCRA Agent GB Trial Burn Report for the Deactivation Furnace System [DFS/GB], Appendices A-J. Prepared for Program Manager for Chemical Demilitarization, April 9, 1997. Tooele, Utah: EG&G Defense Materials, Inc.
EG&G (EG&G Defense Materials, Inc.). 1998. Tooele Chemical Agent Disposal Facility (TOCDF), RCRA Agent Trial Burn Report for the Deactivation Furnace System [DSF/ GB]. Prepared for Southern Research Institute, January 14, 1998. Tooele, Utah: EG&G Defense Materials, Inc.
TRC (TRC Environmental Corporation). 1993a. Results of the Chromium Emissions Test Program on the Deactivation Furnace System Baseline Test Conditions, Chemical Agent Munitions Disposal System (CAMDS), Tooele, Utah [DFS/Propane]. Prepared for Program Manager for Chemical Demilitarization, May 1993. Aberdeen Proving Ground, Md.: U.S. Army Program Manager for Chemical Demilitarization.
TRC. 1993. RCRA Compliance Test Results with Mixed Agent VX/Munitions for the Cryofracture Program on the Deactivation Furnace System, Chemical Agent Munitions Disposal System [DFS/VX]. Prepared for Program Manager for Chemical Demilitarization, October 1993. Aberdeen Proving Ground, Md.: U.S. Army Program Manager for Chemical Demilitarization.
Representative terms from entire chapter:
agent disposal