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Suggested Citation:"Solid Wastes." National Research Council. 1993. Alternative Technologies for the Destruction of Chemical Agents and Munitions. Washington, DC: The National Academies Press. doi: 10.17226/2218.
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Page 82

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REQUIREMENTS AND CONSIDERATIONS FOR CHEMICAL DEMILITARIZATION TECHNOLOGIES 82 TABLE 4-1 Permissible Agent Hazard Concentrations in Air and Lethal Doses Permissible Hazard Levels in Air(mg/m3) Lethal Human Doses Agent Workersa Stack General Skin Intravenous Inhalation Emissionsb Populationc (LD50, mg/ (LD50, mg/kg) (LCt50, mg— kg) min/m3 ) GA 0.0001 0.0003 0.000003 14-21 0.014 135-400 GB 0.0001 0.0003 0.000003 24 0.014 70—100 VX 0.00001 0.0003 0.000003 0.04 0.008 20-50 H/HD/HT 0.003 0.03 0.0001 100 — 10,000 L 0.003 0.03 0.003 — 100,000 a For 8-hour exposure. b Maximum concentration in exhaust stack. c For 72-hour exposure. Note: The Army standards shown in the first three columns set the minimum level of performance required for gas release by any alternative process and are applicable to all four process streams. LCt50 and LD50 represent dosage that result in 50 percent lethality. Source: U.S. Department of the Army (1974, 1975); PEIS (1988). Solid Wastes A major consideration at JACADS is the segregation of waste that may have been contaminated by agent from other hazardous and nonhazardous waste. Waste that is known never to have been contaminated is handled as simple hazardous or nonhazardous waste. The Army has three self-imposed categories of chemical agent contamination of solid wastes: • Level 1X is contaminated material that has not yet been processed or that still has detectable agent according to air monitoring above the material. This material must be controlled according to Army regulations and procedures. • Level 3X was established primarily for worker safety to indicate potentially contaminated material or previously contaminated material that has been decontaminated to show zero residual contamination by air monitoring above the material. Such material includes wood pallets that have

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The U.S. Army Chemical Stockpile Disposal Program was established with the goal of destroying the nation's stockpile of lethal unitary chemical weapons. Since 1990 the U.S. Army has been testing a baseline incineration technology on Johnston Island in the southern Pacific Ocean. Under the planned disposal program, this baseline technology will be imported in the mid to late 1990s to continental United States disposal facilities; construction will include eight stockpile storage sites.

In early 1992 the Committee on Alternative Chemical Demilitarization Technologies was formed by the National Research Council to investigate potential alternatives to the baseline technology. This book, the result of its investigation, addresses the use of alternative destruction technologies to replace, partly or wholly, or to be used in addition to the baseline technology. The book considers principal technologies that might be applied to the disposal program, strategies that might be used to manage the stockpile, and combinations of technologies that might be employed.

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