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Suggested Citation:"REFERENCES." National Research Council. 1989. Research Opportunities for Materials with Ultrafine Microstructures. Washington, DC: The National Academies Press. doi: 10.17226/1488.
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Page 97
Suggested Citation:"REFERENCES." National Research Council. 1989. Research Opportunities for Materials with Ultrafine Microstructures. Washington, DC: The National Academies Press. doi: 10.17226/1488.
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Page 98

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SELECTED APPLICATION AREAS. 97 the other synthesis methods also discussed in Chapters 2 and 3 have the potential for generating similar ultrafine composite structures. MULTILAYER COATINGS. An important structural application of multilayer thin films is as protective coatings for Co-WC cutting tools. A typical composite film comprises three vapor-deposited layers of TiC, TiN, and Al2O3 , each of which performs a specific function that contributes to the overall performance and durability of the cutting tool. The first example of an application of a nanophase-composite coating has inspired much recent activity in the coatings industry to devise and exploit multilayer films for a variety of applications, including protective coatings for mirrors, wear- resistant surfaces on polymers, and low-friction bearings. In this context, particularly intriguing is the low- temperature synthesis of superhard materials such as diamond and cubic BN. An interesting feature of such materials is the inherently nanoscale structure of the deposited films, which themselves are an integral part of a nanoscale architecture. For certain multilayered systems with compatible structures, the possibility exists of generating a strained- layer superlattice that exhibits the supermodulus effect. Exceptionally stiff coatings on stiff substrates have been made for experimental purposes. Potential applications are being considered for producing superstiff coated filaments for reinforcement purposes in composite structures. REFERENCES Cohen, Y., and E. L. Thomas. 1988. Microfibrillator network of a rigid rod polymer: I--Visualization by electron microscopy. Macromolecules 21:433. Croat, J. J., J. F. Herbst, R. W. Lee, and F. E. Pinkerton. 1984a. High-energy product Nd-Fe-B permanent magnets. Appl. Phys. Lett. 44 (1):148–149. Croat, J. J., J. F. Herbst, R. W. Lee, and F. E. Pinkerton. 1984b. Pr-Fe and Nd-Fe-based materials: A new class of high-performance permanent magnets. J. Appl. Phys. 55:2078. Herbst, J. F., J. J. Croat, F. E. Pinkerton, and W. B. Yelon. 1984. Phys. Rev. B. 29:4176. Keem, J. E., G. B. Clements, A. M. Kadin, and R. W. McCallum. 1988. P. 27 in Hard and Soft Magnetic Materials With Applications. Proceedings of a Conference Held in ASM's Materials Week 1987. Metals Park, Ohio: ASM International.

SELECTED APPLICATION AREAS. 98 Koon, N. C., C. M. Williams, and B. N. Das. 1980. 26th Annual Conference on Magnetism and Magnetic Materials, Dallas, Texas, November 11–14. Newnham, R. E., D. P. Skinner, and L. E. Cross. 1978. Mat. Res. Bull. 13:525. Stoner, E. C., and E. P. Wohlfarth. 1948. Philos. Trans. R. Soc. Lond. Ser. A 240:599.

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Materials with nanoscale structure (i.e. a structure of less than 100 nanometers in size) represent a new and exciting field of research. These materials can be produced in many ways, possess a number of unique properties compared with coarser-scaled structures, and have several possible applications with significant technological importance. Based on a state-of-the-art survey of research findings and commercial prospects, this new book concludes that much work remains to be done in characterizing these structures and their exceptional properties, and presents recommendations for the specific research and development activities needed to fill these gaps in our understanding.

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